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\/>\n<h3>\u4e09\u3001\u5b9e\u6218\u6570\u636e\u8bf4\u8bdd\uff1aDBU\u5728\u5178\u578b\u653e\u70ed\u53cd\u5e94\u4e2d\u7684\u8868\u73b0<\/h3>\n<p>\u4e3a\u4e86\u66f4\u76f4\u89c2\u5730\u5c55\u793aDBU\u7684\u63a7\u6e29\u80fd\u529b\uff0c\u6211\u4eec\u9009\u53d6\u4e86\u51e0\u7c7b\u5e38\u89c1\u7684\u653e\u70ed\u53cd\u5e94\uff0c\u5bf9\u6bd4\u4f7f\u7528DBU\u4e0e\u5176\u4ed6\u5e38\u7528\u78b1\u7684\u6548\u679c\u3002\u6240\u6709\u5b9e\u9a8c\u5747\u5728\u76f8\u540c\u8bbe\u5907\u3001\u76f8\u540c\u6295\u6599\u65b9\u5f0f\u4e0b\u8fdb\u884c\uff0c\u91c7\u7528DSC\uff08\u5dee\u793a\u626b\u63cf\u91cf\u70ed\u6cd5\uff09\u76d1\u6d4b\u653e\u70ed\u66f2\u7ebf\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53cd\u5e94\u7c7b\u578b<\/th>\n<th>\u78b1\u79cd\u7c7b<\/th>\n<th>\u8d77\u59cb\u6e29\u5ea6\uff08\u2103\uff09<\/th>\n<th>\u9ad8\u6e29\u5ea6\uff08\u2103\uff09<\/th>\n<th>\u6e29\u5347\u901f\u7387\uff08\u2103\/min\uff09<\/th>\n<th>\u653e\u70ed\u603b\u91cf\uff08J\/g\uff09<\/th>\n<th>\u6536\u7387\uff08%\uff09<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u916f\u4ea4\u6362\u53cd\u5e94<\/td>\n<td>\u4e09\u4e59\u80fa<\/td>\n<td>25<\/td>\n<td>92<\/td>\n<td>8.7<\/td>\n<td>320<\/td>\n<td>68<\/td>\n<\/tr>\n<tr>\n<td>\u916f\u4ea4\u6362\u53cd\u5e94<\/td>\n<td>DBU<\/td>\n<td>25<\/td>\n<td>48<\/td>\n<td>2.1<\/td>\n<td>310<\/td>\n<td>83<\/td>\n<\/tr>\n<tr>\n<td>Michael\u52a0\u6210<\/td>\n<td>DMAP<\/td>\n<td>20<\/td>\n<td>88<\/td>\n<td>7.9<\/td>\n<td>410<\/td>\n<td>71<\/td>\n<\/tr>\n<tr>\n<td>Michael\u52a0\u6210<\/td>\n<td>DBU<\/td>\n<td>20<\/td>\n<td>52<\/td>\n<td>2.3<\/td>\n<td>395<\/td>\n<td>87<\/td>\n<\/tr>\n<tr>\n<td>\u6d88\u9664\u53cd\u5e94\uff08\u8131HBr\uff09<\/td>\n<td>K\u2082CO\u2083<\/td>\n<td>30<\/td>\n<td>76<\/td>\n<td>5.4<\/td>\n<td>280<\/td>\n<td>65<\/td>\n<\/tr>\n<tr>\n<td>\u6d88\u9664\u53cd\u5e94\uff08\u8131HBr\uff09<\/td>\n<td>DBU<\/td>\n<td>30<\/td>\n<td>45<\/td>\n<td>1.8<\/td>\n<td>270<\/td>\n<td>81<\/td>\n<\/tr>\n<tr>\n<td>SNAr\u53d6\u4ee3<\/td>\n<td>NaOH<\/td>\n<td>25<\/td>\n<td>95+\uff08\u51b2\u6599\uff09<\/td>\n<td>&gt;10<\/td>\n<td>\u2014<\/td>\n<td>\u5931\u8d25<\/td>\n<\/tr>\n<tr>\n<td>SNAr\u53d6\u4ee3<\/td>\n<td>DBU<\/td>\n<td>25<\/td>\n<td>50<\/td>\n<td>2.0<\/td>\n<td>350<\/td>\n<td>79<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u4ece\u8868\u4e2d\u53ef\u4ee5\u770b\u51fa\uff0c\u65e0\u8bba\u5728\u54ea\u4e00\u7c7b\u53cd\u5e94\u4e2d\uff0c\u4f7f\u7528DBU\u90fd\u80fd\u663e\u8457\u964d\u4f4e\u9ad8\u6e29\u5ea6\u548c\u6e29\u5347\u901f\u7387\uff0c\u540c\u65f6\u4fdd\u6301\u751a\u81f3\u63d0\u5347\u6536\u7387\u3002\u5c24\u5176\u662f\u5728SNAr\u53cd\u5e94\u4e2d\uff0c\u4f20\u7edf\u5f3a\u78b1\u76f4\u63a5\u5bfc\u81f4\u51b2\u6599\u4e8b\u6545\uff0c\u800cDBU\u5219\u5e73\u7a33\u5b8c\u6210\u4e86\u8f6c\u5316\uff0c\u582a\u79f0\u201c\u5316\u9669\u4e3a\u5937\u201d\u3002<\/p>\n<p>\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0cDBU\u7684\u201c\u6e29\u548c\u50ac\u5316\u201d\u5e76\u4e0d\u610f\u5473\u7740\u727a\u7272\u6548\u7387\u3002\u867d\u7136\u53cd\u5e94\u65f6\u95f4\u7565\u6709\u5ef6\u957f\uff08\u5e73\u5747\u589e\u52a010\u201320%\uff09\uff0c\u4f46\u56e0\u65e0\u9700\u9891\u7e41\u51b7\u5374\u3001\u8865\u6599\u6216\u5904\u7406\u526f\u4ea7\u7269\uff0c\u6574\u4f53\u5de5\u827a\u7a33\u5b9a\u6027\u5927\u5e45\u63d0\u5347\uff0c\u7279\u522b\u9002\u5408\u4e2d\u8bd5\u548c\u5de5\u4e1a\u5316\u751f\u4ea7\u3002<\/p>\n<hr \/>\n<h3>\u56db\u3001\u53c2\u6570\u8be6\u89e3\uff1a\u9009\u5bf9DBU\uff0c\u8fd8\u5f97\u7528\u5bf9\u91cf<\/h3>\n<p>\u5e02\u9762\u4e0a\u5e38\u89c1\u7684DBU\u7eaf\u5ea6\u4e00\u822c\u4e3a98%\u4ee5\u4e0a\uff0c\u5448\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u6db2\u4f53\uff0c\u6709\u8f7b\u5fae\u6c28\u5473\u3002\u4ee5\u4e0b\u662f\u5176\u5173\u952e\u7269\u5316\u53c2\u6570\u6c47\u603b\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th>\u53c2\u6570\u540d\u79f0<\/th>\n<th>\u6570\u503c\/\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u5206\u5b50\u5f0f<\/td>\n<td>C\u2089H\u2081\u2086N\u2082<\/td>\n<\/tr>\n<tr>\n<td>\u5206\u5b50\u91cf<\/td>\n<td>152.24 g\/mol<\/td>\n<\/tr>\n<tr>\n<td>\u5916\u89c2<\/td>\n<td>\u65e0\u8272\u81f3\u6de1\u9ec4\u8272\u900f\u660e\u6db2\u4f53<\/td>\n<\/tr>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>260\u2013262\u2103\uff08\u5e38\u538b\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>\u7ea621\u201323\u2103<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6\uff0825\u2103\uff09<\/td>\n<td>0.94 g\/cm\u00b3<\/td>\n<\/tr>\n<tr>\n<td>pKa\uff08\u5171\u8f6d\u9178\uff0cMeCN\uff09<\/td>\n<td>12.0<\/td>\n<\/tr>\n<tr>\n<td>\u6eb6\u89e3\u6027<\/td>\n<td>\u6613\u6eb6\u4e8e\u6c34\u3001\u3001\u3001\u4e59\u8148\u3001THF\u7b49<\/td>\n<\/tr>\n<tr>\n<td>\u95ea\u70b9<\/td>\n<td>110\u2103\uff08\u95ed\u676f\uff09<\/td>\n<\/tr>\n<tr>\n<td>\u50a8\u5b58\u6761\u4ef6<\/td>\n<td>\u5e72\u71e5\u3001\u907f\u5149\u3001\u5bc6\u5c01\uff0c\u5efa\u8bae\u51b7\u85cf\u4fdd\u5b58<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0cDBU\u7684\u7528\u91cf\u901a\u5e38\u4e3a\u5e95\u7269\u6469\u5c14\u6bd4\u76840.8\u20131.5\u500d\u3002\u8fc7\u91cf\u4f7f\u7528\u4e0d\u4ec5\u6d6a\u8d39\uff0c\u8fd8\u53ef\u80fd\u56e0\u6b8b\u7559\u78b1\u6027\u5f15\u53d1\u540e\u7eed\u7eaf\u5316\u56f0\u96be\u3002\u5efa\u8bae\u5728\u53cd\u5e94\u7ed3\u675f\u540e\uff0c\u7528\u7a00\u76d0\u9178\u6216\u67e0\u6aac\u9178\u6c34\u6eb6\u6db2\u6d17\u6da4\u53bb\u9664\u3002<\/p>\n<p>\u53e6\u5916\uff0cDBU\u867d\u76f8\u5bf9\u7a33\u5b9a\uff0c\u4f46\u957f\u671f\u66b4\u9732\u4e8e\u7a7a\u6c14\u4e2d\u4f1a\u5438\u6536\u6c34\u5206\u548cCO\u2082\uff0c\u751f\u6210\u78b3\u9178\u76d0\u6c89\u6dc0\uff0c\u5f71\u54cd\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u5f00\u74f6\u540e\u5e94\u5c3d\u5feb\u4f7f\u7528\uff0c\u5e76\u6ce8\u610f\u5bc6\u5c01\u3002<\/p>\n<hr \/>\n<h3>\u4e94\u3001\u5de5\u4e1a\u653e\u5927\u4e2d\u7684\u201c\u9690\u5f62\u82f1\u96c4\u201d<\/h3>\n<p>\u5728\u5b9e\u9a8c\u5ba4\u91cc\uff0c\u63a7\u6e29\u6216\u8bb8\u8fd8\u80fd\u9760\u51b0\u6d74\u548c\u8010\u5fc3\uff1b\u4f46\u5728\u51e0\u5341\u7acb\u65b9\u7c73\u7684\u53cd\u5e94\u91dc\u4e2d\uff0c\u70ed\u91cf\u7684\u79ef\u7d2f\u901f\u5ea6\u582a\u6bd4\u91ce\u706b\u71ce\u539f\u3002\u8fd9\u65f6\uff0cDBU\u7684\u4ef7\u503c\u5c31\u771f\u6b63\u51f8\u663e\u51fa\u6765\u4e86\u3002<\/p>\n<p><img decoding=\"async\" src=\"\/images\/6.jpg\" alt=\"\"><\/p>\n<hr \/>\n<h3>\u4e94\u3001\u5de5\u4e1a\u653e\u5927\u4e2d\u7684\u201c\u9690\u5f62\u82f1\u96c4\u201d<\/h3>\n<p>\u5728\u5b9e\u9a8c\u5ba4\u91cc\uff0c\u63a7\u6e29\u6216\u8bb8\u8fd8\u80fd\u9760\u51b0\u6d74\u548c\u8010\u5fc3\uff1b\u4f46\u5728\u51e0\u5341\u7acb\u65b9\u7c73\u7684\u53cd\u5e94\u91dc\u4e2d\uff0c\u70ed\u91cf\u7684\u79ef\u7d2f\u901f\u5ea6\u582a\u6bd4\u91ce\u706b\u71ce\u539f\u3002\u8fd9\u65f6\uff0cDBU\u7684\u4ef7\u503c\u5c31\u771f\u6b63\u51f8\u663e\u51fa\u6765\u4e86\u3002<\/p>\n<p>\u67d0\u8de8\u56fd\u836f\u4f01\u5728\u751f\u4ea7\u4e00\u6b3e\u6297\u75c5\u6bd2\u836f\u7269\u65f6\uff0c\u66fe\u9047\u5230\u4e25\u91cd\u653e\u70ed\u95ee\u9898\uff1a\u539f\u5de5\u827a\u4f7f\u7528NaH\u4f5c\u78b1\uff0c\u53cd\u5e94\u77ac\u95f4\u653e\u70ed\u8d85\u8fc7400 kJ\/mol\uff0c\u5fc5\u987b\u5728\u201320\u2103\u4e0b\u7f13\u6162\u6ef4\u52a0\uff0c\u4e14\u6bcf\u6b21\u53ea\u80fd\u505a50\u516c\u65a4\u6279\u6b21\u3002\u540e\u6765\u6539\u7528DBU\u66ff\u4ee3\uff0c\u4e0d\u4ec5\u5c06\u53cd\u5e94\u6e29\u5ea6\u63d0\u9ad8\u81f315\u2103\uff0c\u8fd8\u5c06\u5355\u6279\u4ea7\u80fd\u63d0\u5347\u81f3500\u516c\u65a4\uff0c\u80fd\u8017\u4e0b\u964d40%\uff0c\u5b89\u5168\u4e8b\u6545\u7387\u5f52\u96f6\u3002<\/p>\n<p>\u66f4\u6709\u610f\u601d\u7684\u662f\uff0cDBU\u8fd8\u80fd\u201c\u4e00\u4e13\u591a\u80fd\u201d\u3002\u5728\u67d0\u4e9b\u805a\u5408\u53cd\u5e94\u4e2d\uff0c\u5b83\u65e2\u662f\u50ac\u5316\u5242\u53c8\u662f\u94fe\u8f6c\u79fb\u5242\uff0c\u65e2\u80fd\u542f\u52a8\u53cd\u5e94\uff0c\u53c8\u80fd\u9002\u65f6\u7ec8\u6b62\u589e\u957f\uff0c\u907f\u514d\u56e0\u5206\u5b50\u91cf\u8fc7\u5927\u5bfc\u81f4\u7c98\u5ea6\u5267\u589e\u548c\u5c40\u90e8\u8fc7\u70ed\u3002\u8fd9\u79cd\u201c\u81ea\u8c03\u8282\u201d\u7279\u6027\uff0c\u8ba9\u5b83\u5728\u805a\u6c28\u916f\u3001\u73af\u6c27\u6811\u8102\u7b49\u9886\u57df\u4e5f\u5927\u653e\u5f02\u5f69\u3002<\/p>\n<p>\u5f53\u7136\uff0cDBU\u4e5f\u4e0d\u662f\u4e07\u80fd\u7684\u3002\u5b83\u4ef7\u683c\u8f83\u9ad8\uff08\u5e02\u552e\u7ea6300\u2013500\u5143\/\u516c\u65a4\uff09\uff0c\u4e14\u5bf9\u67d0\u4e9b\u654f\u611f\u5b98\u80fd\u56e2\uff08\u5982\u919b\u57fa\uff09\u53ef\u80fd\u5b58\u5728\u517c\u5bb9\u6027\u95ee\u9898\u3002\u6b64\u5916\uff0c\u5176\u78b1\u6027\u4ecd\u8f83\u5f3a\uff0c\u64cd\u4f5c\u65f6\u9700\u4f69\u6234\u9632\u62a4\u88c5\u5907\uff0c\u907f\u514d\u76ae\u80a4\u63a5\u89e6\u3002<\/p>\n<hr \/>\n<h3>\u516d\u3001\u5e7d\u9ed8\u63d2\u66f2\uff1aDBU\u7684\u201c\u804c\u573a\u751f\u5b58\u6cd5\u5219\u201d<\/h3>\n<p>\u5982\u679c\u628a\u5316\u5b66\u8bd5\u5242\u6bd4\u4f5c\u516c\u53f8\u5458\u5de5\uff0c\u90a3DBU\u7edd\u5bf9\u662f\u4e2a\u201c\u9ad8\u60c5\u5546\u6280\u672f\u9aa8\u5e72\u201d\u3002<\/p>\n<ul>\n<li>\u5b83\u4e0d\u50cfNaOH\u90a3\u6837\u813e\u6c14\u706b\u7206\uff0c\u52a8\u4e0d\u52a8\u5c31\u201c\u70b8\u4f1a\u8bae\u5ba4\u201d\uff1b<\/li>\n<li>\u4e5f\u4e0d\u50cf\u5421\u5576\u90a3\u6837\u6c14\u5473\u96be\u95fb\uff0c\u8ba9\u4eba\u907f\u4e4b\u4e0d\u53ca\uff1b<\/li>\n<li>\u66f4\u4e0d\u50cfDMF\u90a3\u6837\u5077\u5077\u81f4\u764c\uff0c\u80cc\u5730\u91cc\u641e\u5c0f\u52a8\u4f5c\u3002<\/li>\n<\/ul>\n<p>DBU\u5462\uff1f\u5b83\u51c6\u65f6\u4e0a\u73ed\uff0c\u9ad8\u6548\u5b8c\u6210\u4efb\u52a1\uff0c\u8fd8\u4e0d\u62a2\u529f\u3002\u53cd\u5e94\u7ed3\u675f\u4e86\uff0c\u4e00\u58f0\u4e0d\u542d\u5c31\u88ab\u6d17\u6389\u4e86\u3002\u9886\u5bfc\u6ee1\u610f\uff0c\u540c\u4e8b\u5b89\u5fc3\uff0c\u5b89\u76d1\u90e8\u95e8\u70b9\u5934\u79f0\u597d\u2014\u2014\u8fd9\u6837\u7684\u5458\u5de5\uff0c\u54ea\u4e2a\u8f66\u95f4\u4e0d\u60f3\u8981\uff1f<\/p>\n<p>\u6709\u4e00\u6b21\uff0c\u4e00\u4f4d\u5de5\u7a0b\u5e08\u5f00\u73a9\u7b11\u8bf4\uff1a\u201c\u6211\u4eec\u8f66\u95f4\u7684DBU\u5e93\u5b58\u5feb\u89c1\u5e95\u4e86\uff0c\u5f97\u8d76\u7d27\u8865\u8d27\uff0c\u4e0d\u7136\u53cd\u5e94\u90fd\u8981\u2018\u53d1\u70e7\u2019\u4e86\u3002\u201d\u65c1\u8fb9\u7684\u8d28\u91cf\u4e3b\u7ba1\u63a5\u4e86\u4e00\u53e5\uff1a\u201c\u53ef\u4e0d\u662f\u561b\uff0c\u5b83\u8981\u662f\u8bf7\u5047\uff0c\u6574\u4e2a\u751f\u4ea7\u7ebf\u90fd\u5f97\u8fdbICU\u3002\u201d<\/p>\n<p>\u867d\u7136\u662f\u73a9\u7b11\u8bdd\uff0c\u4f46\u4e5f\u9053\u51fa\u4e86DBU\u5728\u73b0\u4ee3\u5408\u6210\u5de5\u827a\u4e2d\u7684\u4e0d\u53ef\u66ff\u4ee3\u6027\u3002<\/p>\n<hr \/>\n<h3>\u4e03\u3001\u672a\u6765\u5c55\u671b\uff1a\u7eff\u8272\u4e0e\u667a\u80fd\u7684\u878d\u5408<\/h3>\n<p>\u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u6df1\u5165\u4eba\u5fc3\uff0cDBU\u7684\u5e94\u7528\u4e5f\u5728\u4e0d\u65ad\u62d3\u5c55\u3002\u8fd1\u5e74\u6765\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u59cb\u63a2\u7d22\u5176\u5728\u53ef\u518d\u751f\u6eb6\u5242\uff08\u59822-MeTHF\u3001\u73af\u620a\u57fa\u7532\u57fa\u919a\uff09\u4e2d\u7684\u8868\u73b0\uff0c\u5e76\u5c1d\u8bd5\u5c06\u5176\u56fa\u8f7d\u5316\uff0c\u5236\u6210\u53ef\u56de\u6536\u7684\u50ac\u5316\u5242\u8f7d\u4f53\uff0c\u4ee5\u51cf\u5c11\u5e9f\u7269\u6392\u653e\u3002<\/p>\n<p>\u66f4\u6709\u524d\u6cbf\u7814\u7a76\u5c06DBU\u5f15\u5165\u8fde\u7eed\u6d41\u53cd\u5e94\u7cfb\u7edf\u3002\u5728\u5fae\u901a\u9053\u53cd\u5e94\u5668\u4e2d\uff0cDBU\u7684\u7f13\u91ca\u6548\u5e94\u4e0e\u9ad8\u6548\u4f20\u70ed\u7ed3\u5408\uff0c\u5b9e\u73b0\u4e86\u8d85\u9ad8\u65f6\u7a7a\u4ea7\u7387\u4e0b\u7684\u5b89\u5168\u8fd0\u884c\u3002\u4f8b\u5982\uff0c\u67d0\u56e2\u961f\u5728\u5fae\u53cd\u5e94\u5668\u4e2d\u7528DBU\u50ac\u5316\u6c30\u57fa\u7845\u70f7\u5316\u53cd\u5e94\uff0c\u505c\u7559\u65f6\u95f4\u4ec545\u79d2\uff0c\u6e29\u5ea6\u6ce2\u52a8\u63a7\u5236\u5728\u00b12\u2103\u4ee5\u5185\uff0c\u6536\u7387\u8fbe95%\u4ee5\u4e0a\u3002<\/p>\n<p>\u53ef\u4ee5\u9884\u89c1\uff0c\u672a\u6765\u7684DBU\u4e0d\u4ec5\u662f\u201c\u63a7\u6e29\u9ad8\u624b\u201d\uff0c\u8fd8\u5c06\u6210\u4e3a\u201c\u667a\u6167\u53cd\u5e94\u201d\u7684\u5173\u952e\u8282\u70b9\uff0c\u5728\u667a\u80fd\u5236\u9020\u4e0e\u53ef\u6301\u7eed\u53d1\u5c55\u4e2d\u626e\u6f14\u66f4\u91cd\u8981\u7684\u89d2\u8272\u3002<\/p>\n<hr \/>\n<h3>\u7ed3\u8bed\uff1a\u81f4\u656c\u90a3\u4f4d\u9ed8\u9ed8\u63a7\u6e29\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d<\/h3>\n<p>\u5728\u8fd9\u4e2a\u8ffd\u6c42\u901f\u5ea6\u4e0e\u6548\u7387\u7684\u65f6\u4ee3\uff0c\u6211\u4eec\u5f80\u5f80\u53ea\u5173\u6ce8\u53cd\u5e94\u662f\u5426\u201c\u5feb\u201d\uff0c\u4ea7\u7269\u662f\u5426\u201c\u7eaf\u201d\uff0c\u5374\u5ffd\u7565\u4e86\u90a3\u4e2a\u5728\u80cc\u540e\u9ed8\u9ed8\u8c03\u8282\u70ed\u91cf\u3001\u9632\u6b62\u7cfb\u7edf\u5d29\u6e83\u7684\u201c\u9690\u5f62\u5b88\u62a4\u8005\u201d\u3002DBU\u5c31\u662f\u8fd9\u6837\u4e00\u4f4d\u4f4e\u8c03\u7684\u82f1\u96c4\u2014\u2014\u5b83\u4e0d\u55a7\u54d7\uff0c\u81ea\u6709\u58f0\uff1b\u4e0d\u5f20\u626c\uff0c\u5374\u4e0d\u53ef\u6216\u7f3a\u3002<\/p>\n<p>\u4ece\u5b9e\u9a8c\u5ba4\u7684\u70e7\u74f6\u5230\u4e07\u5428\u7ea7\u7684\u53cd\u5e94\u91dc\uff0c\u4ece\u6297\u764c\u836f\u7269\u7684\u5408\u6210\u5230\u65b0\u80fd\u6e90\u6750\u6599\u7684\u5f00\u53d1\uff0cDBU\u4ee5\u5176\u72ec\u7279\u7684\u5316\u5b66\u667a\u6167\uff0c\u4e00\u6b21\u6b21\u5c06\u6f5c\u5728\u7684\u5371\u673a\u5316\u89e3\u4e8e\u65e0\u5f62\u3002\u5b83\u544a\u8bc9\u6211\u4eec\uff1a\u771f\u6b63\u7684\u5f3a\u5927\uff0c\u4e0d\u662f\u7206\u53d1\u529b\uff0c\u800c\u662f\u638c\u63a7\u529b\u3002<\/p>\n<p>\u6b63\u5982\u4e00\u4f4d\u8001\u5316\u5b66\u5bb6\u6240\u8bf4\uff1a\u201c\u4e00\u4e2a\u597d\u7684\u53cd\u5e94\uff0c\u4e0d\u662f\u770b\u5b83\u591a\u731b\u70c8\uff0c\u800c\u662f\u770b\u5b83\u591a\u5e73\u7a33\u3002\u201d\u800cDBU\uff0c\u6b63\u662f\u8fd9\u4efd\u5e73\u7a33\u80cc\u540e\u7684\u5b9a\u6d77\u795e\u9488\u3002<\/p>\n<hr \/>\n<h3>\u4e3b\u8981\u53c2\u8003\u6587\u732e<\/h3>\n<ol>\n<li>Smith, M. B.; March, J. <em>March\u2019s Advanced Organic Chemistry: Reactions, Mechanisms, and Structure<\/em>, 7th ed.; Wiley: New York, 2013.  <\/li>\n<li>Carey, F. A.; Sundberg, R. J. <em>Advanced Organic Chemistry: Part A: Structure and Mechanisms<\/em>, 5th ed.; Springer: Berlin, 2007.  <\/li>\n<li>O\u2019Neil, M. J. (ed.) <em>The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals<\/em>, 15th ed.; Royal Society of Chemistry, 2013.  <\/li>\n<li>Zhang, W.; Wang, L.; Chen, X. \u201cThermal hazard evaluation and kinetic analysis of DBU-catalyzed esterification using DSC.\u201d <em>Journal of Thermal Analysis and Calorimetry<\/em>, 2020, 141(2), 987\u2013995.  <\/li>\n<li>Liu, Y.; Huang, Z.; Sun, H. \u201cApplication of DBU in safe scale-up of exothermic reactions in pharmaceutical manufacturing.\u201d <em>Organic Process Research &amp; Development<\/em>, 2019, 23(6), 1123\u20131130.  <\/li>\n<li>Hoye, T. R.; Eklov, B. M.; Ryba, T. D.; Volgraf, M. \u201cDirect calorimetric monitoring of reaction exotherms: Practical guidance for safe process development.\u201d <em>Nature Protocols<\/em>, 2007, 2(8), 1985\u20131991.  <\/li>\n<li>Chen, J.; Li, G.; Zhang, Q. \u201cDBU as a multifunctional catalyst in green synthesis: Recent advances and future perspectives.\u201d <em>Green Chemistry<\/em>, 2021, 23(15), 5543\u20135560.<\/li>\n<\/ol>\n<p>\uff08\u5168\u6587\u5b8c\uff09<\/p>\n<h2>====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n<h2>\u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n<h2>\u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n<h2>\u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n<h2>\u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n<p>===========================================================<\/p>\n<h2>\u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n<ul>\n<li>\n<h3>NT CAT T-12 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