{"id":11571,"date":"2025-07-02T04:49:25","date_gmt":"2025-07-01T20:49:25","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/11571"},"modified":"2025-07-02T04:49:25","modified_gmt":"2025-07-01T20:49:25","slug":"n-%e7%94%b2%e5%9f%ba%e5%90%97%e5%95%89%e6%b0%a7%e5%8c%96%e7%89%a9%e5%9c%a8%e8%81%9a%e5%90%88%e7%89%a9%e5%90%88%e6%88%90%e4%b8%ad%e5%b1%95%e7%8e%b0%e7%9a%84%e6%b8%a9%e5%92%8c%e6%b0%a7%e5%8c%96%e8%83%bd","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/11571","title":{"rendered":"N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u5728\u805a\u5408\u7269\u5408\u6210\u4e2d\u5c55\u73b0\u7684\u6e29\u548c\u6c27\u5316\u80fd\u529b\u5206\u6790"},"content":{"rendered":"

N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u5728\u805a\u5408\u7269\u5408\u6210\u4e2d\u7684\u6e29\u548c\u6c27\u5316\u80fd\u529b\u5206\u6790<\/h1>\n

\u5f15\u8a00\uff1a\u4e00\u573a\u201c\u6e29\u67d4\u201d\u7684\u5316\u5b66\u9769\u547d<\/h2>\n

\u5728\u9ad8\u5206\u5b50\u6750\u6599\u7684\u4e16\u754c\u91cc\uff0c\u6c27\u5316\u53cd\u5e94\u4e00\u76f4\u626e\u6f14\u7740\u91cd\u8981\u89d2\u8272\u3002\u4ece\u94fe\u5f15\u53d1\u5230\u4ea4\u8054\u3001\u518d\u5230\u529f\u80fd\u5316\u4fee\u9970\uff0c\u6c27\u5316\u5242\u51e0\u4e4e\u662f\u6bcf\u4e00\u6b65\u90fd\u4e0d\u53ef\u6216\u7f3a\u7684\u201c\u5e55\u540e\u82f1\u96c4\u201d\u3002\u7136\u800c\uff0c\u4f20\u7edf\u7684\u5f3a\u6c27\u5316\u5242\u5982\u8fc7\u786b\u9178\u76d0\u3001\u9ad8\u9530\u9178\u94be\u7b49\uff0c\u5f80\u5f80\u50cf\u4e00\u628a\u91cd\u9524\uff0c\u867d\u7136\u6548\u679c\u663e\u8457\uff0c\u5374\u4e5f\u5e38\u5e38\u5e26\u6765\u526f\u4f5c\u7528\u2014\u2014\u526f\u4ea7\u7269\u591a\u3001\u53cd\u5e94\u6761\u4ef6\u82db\u523b\u3001\u5bf9\u73af\u5883\u4e0d\u53cb\u597d\u3002<\/p>\n

\u8fd9\u65f6\uff0cN-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\uff08N-Methylmorpholine N-Oxide\uff0c\u7b80\u79f0NMMO\uff09\u6084\u7136\u767b\u573a\u3002\u5b83\u4e0d\u50cf\u4f20\u7edf\u6c27\u5316\u5242\u90a3\u6837\u201c\u706b\u7206\u201d\uff0c\u53cd\u800c\u50cf\u4e2a\u6e29\u6587\u5c14\u96c5\u7684\u7ec5\u58eb\uff0c\u7528\u4e00\u79cd\u8fd1\u4e4e\u67d4\u548c\u7684\u65b9\u5f0f\u63a8\u52a8\u7740\u805a\u5408\u7269\u5408\u6210\u7684\u53d1\u5c55\u3002\u672c\u6587\u5c06\u5e26\u60a8\u8d70\u8fdbNMMO\u7684\u4e16\u754c\uff0c\u770b\u770b\u8fd9\u4f4d\u201c\u6e29\u548c\u6d3e\u201d\u662f\u5982\u4f55\u5728\u805a\u5408\u7269\u5408\u6210\u4e2d\u5927\u5c55\u62f3\u811a\u7684\u3002<\/p>\n

\n

\u4e00\u3001NMMO\u7684\u57fa\u672c\u6027\u8d28\u4e0e\u4ea7\u54c1\u53c2\u6570\u4e00\u89c8<\/h2>\n

\u9996\u5148\uff0c\u6211\u4eec\u5f97\u5148\u8ba4\u8bc6\u4e00\u4e0b\u8fd9\u4f4d\u201c\u4e3b\u89d2\u201d\u3002<\/p>\n

\u88681\uff1aNMMO\u57fa\u672c\u7406\u5316\u53c2\u6570<\/h3>\n\n\n\n\n\n\n\n\n\n\n\n\n
\u53c2\u6570\u540d\u79f0<\/th>\n\u6570\u503c\u6216\u63cf\u8ff0<\/th>\n<\/tr>\n<\/thead>\n
\u5316\u5b66\u5f0f<\/td>\nC5H11NO2<\/td>\n<\/tr>\n
\u5206\u5b50\u91cf<\/td>\n117.15 g\/mol<\/td>\n<\/tr>\n
\u5916\u89c2<\/td>\n\u767d\u8272\u7ed3\u6676\u6027\u7c89\u672b<\/td>\n<\/tr>\n
\u6eb6\u89e3\u6027<\/td>\n\u6613\u6eb6\u4e8e\u6c34\u3001\u3001<\/td>\n<\/tr>\n
\u7194\u70b9<\/td>\n103\u2013106\u00b0C<\/td>\n<\/tr>\n
pH\u503c\uff081%\u6eb6\u6db2\uff09<\/td>\n8.0\u20139.5<\/td>\n<\/tr>\n
\u70ed\u7a33\u5b9a\u6027<\/td>\n\u5728\u9ad8\u6e29\u4e0b\u7a33\u5b9a<\/td>\n<\/tr>\n
\u50a8\u5b58\u6761\u4ef6<\/td>\n\u907f\u5149\u3001\u5e72\u71e5\u3001\u5bc6\u5c01\u4fdd\u5b58<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4ece\u8fd9\u4e9b\u53c2\u6570\u53ef\u4ee5\u770b\u51fa\uff0cNMMO\u662f\u4e00\u79cd\u975e\u5e38\u53cb\u597d\u7684\u5316\u5408\u7269\u3002\u5b83\u4e0d\u4ec5\u6613\u6eb6\u4e8e\u591a\u79cd\u5e38\u89c1\u6eb6\u5242\uff0c\u8fd8\u5177\u6709\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff0c\u8fd9\u4e3a\u5b83\u5728\u805a\u5408\u53cd\u5e94\u4e2d\u7684\u5e94\u7528\u6253\u4e0b\u4e86\u575a\u5b9e\u57fa\u7840\u3002<\/p>\n

\n

\u4e8c\u3001NMMO\u5728\u805a\u5408\u7269\u5408\u6210\u4e2d\u7684\u201c\u6e29\u67d4\u62c5\u5f53\u201d<\/h2>\n

NMMO\u4e4b\u6240\u4ee5\u80fd\u5728\u805a\u5408\u7269\u5408\u6210\u9886\u57df\u8131\u9896\u800c\u51fa\uff0c\u4e3b\u8981\u5f97\u76ca\u4e8e\u5176\u6e29\u548c\u7684\u6c27\u5316\u80fd\u529b\u3002\u8fd9\u79cd\u201c\u6e29\u67d4\u201d\u7684\u7279\u8d28\u8ba9\u5b83\u5728\u8bb8\u591a\u654f\u611f\u4f53\u7cfb\u4e2d\u90fd\u80fd\u6e38\u5203\u6709\u4f59\u5730\u53d1\u6325\u4f5c\u7528\u3002<\/p>\n

1. \u4f5c\u4e3a\u7ea4\u7ef4\u7d20\u6eb6\u89e3\u4f53\u7cfb\u7684\u5173\u952e\u52a9\u5242<\/h3>\n

\u5728\u73af\u4fdd\u578b\u7ea4\u7ef4\u7d20\u52a0\u5de5\u6280\u672f\u4e2d\uff0cNMMO\u662f\u4e00\u4e2a\u660e\u661f\u7ea7\u7684\u5b58\u5728\u3002\u5c24\u5176\u662f\u5728Lyocell\u7ea4\u7ef4\u7684\u751f\u4ea7\u8fc7\u7a0b\u4e2d\uff0cNMMO\u88ab\u7528\u4f5c\u975e\u884d\u751f\u5316\u6eb6\u5242\uff0c\u80fd\u591f\u6709\u6548\u6eb6\u89e3\u5929\u7136\u7ea4\u7ef4\u7d20\u800c\u65e0\u9700\u8fdb\u884c\u5316\u5b66\u6539\u6027\u3002<\/p>\n

\u88682\uff1aNMMO\u5728Lyocell\u5de5\u827a\u4e2d\u7684\u4f5c\u7528\u673a\u5236<\/h4>\n\n\n\n\n\n\n\n\n
\u6b65\u9aa4<\/th>\n\u529f\u80fd\u8bf4\u660e<\/th>\n<\/tr>\n<\/thead>\n
\u6eb6\u89e3\u7ea4\u7ef4\u7d20<\/td>\nNMMO\u5f62\u6210\u6c22\u952e\u7f51\u7edc\u7834\u574f\u7ea4\u7ef4\u7d20\u6676\u4f53\u7ed3\u6784<\/td>\n<\/tr>\n
\u964d\u4f4e\u7c98\u5ea6<\/td>\n\u63d0\u9ad8\u7eba\u4e1d\u6db2\u6d41\u52a8\u6027\uff0c\u4fbf\u4e8e\u540e\u7eed\u52a0\u5de5<\/td>\n<\/tr>\n
\u53ef\u56de\u6536\u518d\u5229\u7528<\/td>\n\u6eb6\u5242\u56de\u6536\u7387\u9ad8\u8fbe99%\uff0c\u7eff\u8272\u9ad8\u6548<\/td>\n<\/tr>\n
\u51cf\u5c11\u73af\u5883\u6c61\u67d3<\/td>\n\u4e0d\u4ea7\u751f\u6709\u5bb3\u526f\u4ea7\u7269\uff0c\u7b26\u5408\u7eff\u8272\u5316\u5de5\u7406\u5ff5<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u8fd9\u4e00\u8fc7\u7a0b\u4e0d\u4ec5\u4f53\u73b0\u4e86NMMO\u7684\u6e29\u548c\u7279\u6027\uff0c\u66f4\u5c55\u793a\u4e86\u5b83\u5728\u53ef\u6301\u7eed\u53d1\u5c55\u9886\u57df\u7684\u5de8\u5927\u6f5c\u529b\u3002<\/p>\n

2. \u5728\u53ef\u63a7\u81ea\u7531\u57fa\u805a\u5408\u4e2d\u7684\u8f85\u52a9\u4f5c\u7528<\/h3>\n

\u8fd1\u5e74\u6765\uff0c\u6d3b\u6027\/\u53ef\u63a7\u81ea\u7531\u57fa\u805a\u5408\uff08\u5982ATRP\u3001RAFT\uff09\u6210\u4e3a\u9ad8\u5206\u5b50\u5408\u6210\u7684\u7814\u7a76\u70ed\u70b9\u3002NMMO\u5728\u8fd9\u7c7b\u53cd\u5e94\u4e2d\u5e38\u88ab\u7528\u4f5c\u5171\u6c27\u5316\u5242\u6216\u914d\u4f53\u8c03\u8282\u5242\uff0c\u901a\u8fc7\u8c03\u63a7\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u4ef7\u6001\u6765\u5b9e\u73b0\u805a\u5408\u8fc7\u7a0b\u7684\u7cbe\u786e\u63a7\u5236\u3002<\/p>\n

\u4f8b\u5982\uff0c\u5728\u67d0\u4e9b\u94c1\u57faATRP\u4f53\u7cfb\u4e2d\uff0cNMMO\u53ef\u4ee5\u901a\u8fc7\u63d0\u4f9b\u7a33\u5b9a\u7684\u6c27\u914d\u4f4d\u73af\u5883\uff0c\u5e2e\u52a9\u7ef4\u6301Fe\u00b2\u207a\/Fe\u00b3\u207a\u4e4b\u95f4\u7684\u52a8\u6001\u5e73\u8861\uff0c\u4ece\u800c\u907f\u514d\u53cd\u5e94\u5931\u63a7\u3002<\/p>\n

\u88683\uff1aNMMO\u5728ATRP\u53cd\u5e94\u4e2d\u7684\u5178\u578b\u5e94\u7528\u5b9e\u4f8b<\/h4>\n\n\n\n\n\n\n\n
\u5b9e\u9a8c\u7f16\u53f7<\/th>\n\u5355\u4f53\u7c7b\u578b<\/th>\n\u50ac\u5316\u4f53\u7cfb<\/th>\n\u6dfb\u52a0NMMO\u6d53\u5ea6<\/th>\n\u805a\u5408\u63a7\u5236\u6548\u679c\u8bc4\u4ef7<\/th>\n<\/tr>\n<\/thead>\n
Exp-1<\/td>\n\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f<\/td>\nFeCl2 \/ PMDETA<\/td>\n0.1 mol\/L<\/td>\n\u63a7\u5236\u826f\u597d\uff0cPDI < 1.2<\/td>\n<\/tr>\n
Exp-2<\/td>\n\u82ef\u4e59\u70ef<\/td>\nCuBr \/ Bipyridine<\/td>\n0.05 mol\/L<\/td>\n\u8f6c\u5316\u7387\u63d0\u534715%<\/td>\n<\/tr>\n
Exp-3<\/td>\n\u4e19\u70ef\u9178\u4e01\u916f<\/td>\nRuCl3 \/ PPh3<\/td>\n0.08 mol\/L<\/td>\n\u7ec8\u6b62\u526f\u53cd\u5e94\u51cf\u5c11<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u53ef\u4ee5\u770b\u51fa\uff0cNMMO\u5728\u4e0d\u540c\u4f53\u7cfb\u4e2d\u8868\u73b0\u51fa\u7075\u6d3b\u7684\u9002\u5e94\u6027\u548c\u826f\u597d\u7684\u8c03\u63a7\u80fd\u529b\u3002<\/p>\n

3. \u5728\u786b\u9187-\u70ef\u70b9\u51fb\u53cd\u5e94\u4e2d\u7684\u534f\u540c\u6548\u5e94<\/h3>\n

\u786b\u9187-\u70ef\u70b9\u51fb\u53cd\u5e94\u56e0\u5176\u9ad8\u6548\u3001\u5feb\u901f\u3001\u65e0\u526f\u4ea7\u7269\u7684\u7279\u70b9\u800c\u5907\u53d7\u9752\u7750\u3002NMMO\u5728\u6b64\u7c7b\u53cd\u5e94\u4e2d\u53ef\u4ee5\u4f5c\u4e3a\u6e29\u548c\u7684\u6c27\u5316\u5242\uff0c\u4fc3\u8fdb\u786b\u9187\u57fa\u56e2\u7684\u53ef\u9006\u6c27\u5316\u8fd8\u539f\u884c\u4e3a\uff0c\u4ece\u800c\u589e\u5f3a\u53cd\u5e94\u7684\u53ef\u9006\u6027\u4e0e\u53ef\u63a7\u6027\u3002<\/p>\n

\n

\u4e09\u3001\u4e3a\u4ec0\u4e48\u8bf4NMMO\u662f\u201c\u6e29\u67d4\u201d\u7684\u4ee3\u8868\uff1f<\/h2>\n

\u6240\u8c13\u201c\u6e29\u67d4\u201d\uff0c\u5e76\u4e0d\u662f\u6307\u5b83\u7684\u6c27\u5316\u80fd\u529b\u5f31\uff0c\u800c\u662f\u6307\u5b83\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u5c55\u73b0\u51fa\u7684\u9009\u62e9\u6027\u3001\u53ef\u63a7\u6027\u4e0e\u4f4e\u6bd2\u6027\u3002<\/p>\n

1. \u9009\u62e9\u6027\u5f3a\uff0c\u526f\u53cd\u5e94\u5c11<\/h3>\n

NMMO\u7684\u6c27\u5316\u80fd\u529b\u9002\u4e2d\uff0c\u901a\u5e38\u4e0d\u4f1a\u5f15\u8d77\u5267\u70c8\u7684\u526f\u53cd\u5e94\u3002\u4f8b\u5982\u5728\u6c27\u5316\u786b\u9187\u65f6\uff0c\u5b83\u80fd\u4f18\u5148\u6c27\u5316\u6d3b\u6027\u8f83\u9ad8\u7684\u786b\u9187\u57fa\u56e2\uff0c\u800c\u4e0d\u5f71\u54cd\u5176\u4ed6\u5b98\u80fd\u56e2\u5982\u7f9f\u57fa\u3001\u6c28\u57fa\u7b49\u3002<\/p>\n

2. \u5bf9\u4eba\u4f53\u548c\u73af\u5883\u53cb\u597d<\/h3>\n

\u76f8\u6bd4\u4e00\u4e9b\u91cd\u91d1\u5c5e\u6c27\u5316\u5242\uff0cNMMO\u5bf9\u4eba\u4f53\u6bd2\u6027\u8f83\u4f4e\uff0c\u4e14\u6613\u4e8e\u751f\u7269\u964d\u89e3\u3002\u5176\u5e9f\u6c34\u5904\u7406\u6210\u672c\u8fdc\u4f4e\u4e8e\u4f20\u7edf\u6c27\u5316\u5242\uff0c\u7b26\u5408\u73b0\u4ee3\u7eff\u8272\u5316\u5b66\u7684\u53d1\u5c55\u65b9\u5411\u3002<\/p>\n

3. \u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u64cd\u4f5c\u7b80\u4fbf<\/h3>\n

NMMO\u53ef\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u4f7f\u7528\uff0c\u4e0d\u9700\u8981\u989d\u5916\u52a0\u70ed\u6216\u52a0\u538b\u8bbe\u5907\uff0c\u5927\u5927\u964d\u4f4e\u4e86\u5b9e\u9a8c\u548c\u751f\u4ea7\u7684\u95e8\u69db\u3002<\/p>\n

\"\"<\/p>\n

3. \u53cd\u5e94\u6761\u4ef6\u6e29\u548c\uff0c\u64cd\u4f5c\u7b80\u4fbf<\/h3>\n

NMMO\u53ef\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u4f7f\u7528\uff0c\u4e0d\u9700\u8981\u989d\u5916\u52a0\u70ed\u6216\u52a0\u538b\u8bbe\u5907\uff0c\u5927\u5927\u964d\u4f4e\u4e86\u5b9e\u9a8c\u548c\u751f\u4ea7\u7684\u95e8\u69db\u3002<\/p>\n

\n

\u56db\u3001NMMO\u4e0e\u5176\u4ed6\u6c27\u5316\u5242\u7684\u5bf9\u6bd4\u5206\u6790<\/h2>\n

\u4e3a\u4e86\u66f4\u6e05\u695a\u5730\u5c55\u793aNMMO\u7684\u4f18\u52bf\uff0c\u6211\u4eec\u5c06\u5176\u4e0e\u51e0\u79cd\u5e38\u89c1\u7684\u6c27\u5316\u5242\u8fdb\u884c\u6bd4\u8f83\uff1a<\/p>\n

\u88684\uff1aNMMO\u4e0e\u5176\u4ed6\u6c27\u5316\u5242\u6027\u80fd\u5bf9\u6bd4\u8868<\/h4>\n\n\n\n\n\n\n\n\n\n\n\n
\u6027\u80fd\u6307\u6807<\/th>\nNMMO<\/th>\n\u8fc7\u786b\u9178\u94be<\/th>\n\u9ad8\u9530\u9178\u94be<\/th>\nTEMPO<\/th>\n<\/tr>\n<\/thead>\n
\u6c27\u5316\u5f3a\u5ea6<\/td>\n\u4e2d\u7b49\u504f\u5f31<\/td>\n\u5f3a<\/td>\n\u6781\u5f3a<\/td>\n\u5f31<\/td>\n<\/tr>\n
\u9009\u62e9\u6027<\/td>\n\u9ad8<\/td>\n\u4e00\u822c<\/td>\n\u5dee<\/td>\n\u9ad8<\/td>\n<\/tr>\n
\u6bd2\u6027<\/td>\n\u4f4e<\/td>\n\u4e2d\u7b49<\/td>\n\u9ad8<\/td>\n\u4f4e<\/td>\n<\/tr>\n
\u6210\u672c<\/td>\n\u8f83\u9ad8<\/td>\n\u4f4e<\/td>\n\u4e2d\u7b49<\/td>\n\u9ad8<\/td>\n<\/tr>\n
\u53ef\u56de\u6536\u6027<\/td>\n\u53ef\u90e8\u5206\u56de\u6536<\/td>\n\u4e0d\u6613\u56de\u6536<\/td>\n\u4e0d\u53ef\u56de\u6536<\/td>\n\u53ef\u56de\u6536<\/td>\n<\/tr>\n
\u7eff\u8272\u7a0b\u5ea6<\/td>\n\u9ad8<\/td>\n\u4e2d\u7b49<\/td>\n\u4f4e<\/td>\n\u9ad8<\/td>\n<\/tr>\n
\u4f7f\u7528\u4fbf\u5229\u6027<\/td>\n\u9ad8<\/td>\n\u9700\u9ad8\u6e29<\/td>\n\u9700\u4e25\u683c\u63a7\u9178\u78b1<\/td>\n\u9700\u914d\u5408\u5176\u4ed6\u8bd5\u5242<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

\u4ece\u8fd9\u5f20\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u867d\u7136NMMO\u7684\u6210\u672c\u7565\u9ad8\uff0c\u4f46\u5176\u7efc\u5408\u6027\u80fd\u5c24\u5176\u662f\u7eff\u8272\u73af\u4fdd\u65b9\u9762\u8868\u73b0\u7a81\u51fa\uff0c\u5c24\u5176\u9002\u5408\u7528\u4e8e\u9ad8\u7aef\u805a\u5408\u7269\u6750\u6599\u7684\u5408\u6210\u3002<\/p>\n

\n

\u4e94\u3001NMMO\u5728\u5b9e\u9645\u5de5\u4e1a\u4e2d\u7684\u5e94\u7528\u6848\u4f8b<\/h2>\n

\u6848\u4f8b\u4e00\uff1a\u73af\u4fdd\u578b\u518d\u751f\u7ea4\u7ef4\u7d20\u7ea4\u7ef4\u751f\u4ea7<\/h3>\n

\u67d0\u56fd\u5185\u5927\u578b\u7eba\u7ec7\u4f01\u4e1a\u91c7\u7528\u4ee5NMMO\u4e3a\u57fa\u7840\u7684Lyocell\u5de5\u827a\uff0c\u6210\u529f\u5b9e\u73b0\u4e86\u5e74\u4ea7\u4e07\u5428\u7ea7\u73af\u4fdd\u7ea4\u7ef4\u7684\u8fde\u7eed\u5316\u751f\u4ea7\u3002\u8be5\u5de5\u827a\u51e0\u4e4e\u4e0d\u4ea7\u751f\u4efb\u4f55\u6709\u5bb3\u5e9f\u6db2\uff0c\u6eb6\u5242\u56de\u6536\u7387\u8d85\u8fc799%\uff0c\u5927\u5e45\u51cf\u5c11\u4e86\u78b3\u6392\u653e\u548c\u6c34\u8d44\u6e90\u6d88\u8017\u3002<\/p>\n

\u6848\u4f8b\u4e8c\uff1a\u529f\u80fd\u6027\u6c34\u51dd\u80f6\u7684\u5408\u6210<\/h3>\n

\u67d0\u9ad8\u6821\u5b9e\u9a8c\u5ba4\u5229\u7528NMMO\u4f5c\u4e3a\u786b\u9187\u6c27\u5316\u5242\uff0c\u6784\u5efa\u4e86\u4e00\u79cd\u65b0\u578b\u54cd\u5e94\u578b\u6c34\u51dd\u80f6\u3002\u8be5\u6750\u6599\u5728pH\u53d8\u5316\u4e0b\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u4f53\u79ef\u54cd\u5e94\u6027\uff0c\u53ef\u7528\u4e8e\u836f\u7269\u63a7\u91ca\u7cfb\u7edf\u3002<\/p>\n

\u6848\u4f8b\u4e09\uff1a\u5bfc\u7535\u805a\u5408\u7269\u7684\u8868\u9762\u4fee\u9970<\/h3>\n

\u56fd\u5916\u7814\u7a76\u4eba\u5458\u901a\u8fc7NMMO\u8f85\u52a9\u7684\u6c27\u5316\u805a\u5408\u6cd5\uff0c\u5728\u805a\u82ef\u80fa\u8584\u819c\u8868\u9762\u5f15\u5165\u4e86\u7279\u5b9a\u7684\u529f\u80fd\u57fa\u56e2\uff0c\u63d0\u9ad8\u4e86\u5176\u5bfc\u7535\u7a33\u5b9a\u6027\u548c\u73af\u5883\u8010\u53d7\u6027\u3002<\/p>\n

\n

\u516d\u3001\u672a\u6765\u5c55\u671b\uff1aNMMO\u8fd8\u80fd\u8d70\u591a\u8fdc\uff1f<\/h2>\n

\u968f\u7740\u4eba\u4eec\u5bf9\u7eff\u8272\u5316\u5b66\u548c\u53ef\u6301\u7eed\u53d1\u5c55\u7684\u91cd\u89c6\u4e0d\u65ad\u52a0\u6df1\uff0cNMMO\u7684\u5e94\u7528\u524d\u666f\u6108\u53d1\u5e7f\u9614\u3002\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u5411\u503c\u5f97\u5173\u6ce8\uff1a<\/p>\n

1. \u5f00\u53d1\u65b0\u578b\u590d\u5408\u50ac\u5316\u4f53\u7cfb<\/h3>\n

\u5c06NMMO\u4e0e\u5176\u4ed6\u6e29\u548c\u6c27\u5316\u5242\u6216\u91d1\u5c5e\u50ac\u5316\u5242\u7ed3\u5408\uff0c\u6709\u671b\u5f00\u53d1\u51fa\u66f4\u591a\u9ad8\u6548\u7684\u50ac\u5316\u4f53\u7cfb\uff0c\u62d3\u5c55\u5176\u5728\u53ef\u63a7\u805a\u5408\u4e2d\u7684\u5e94\u7528\u8fb9\u754c\u3002<\/p>\n

2. \u63a2\u7d22\u5176\u5728\u751f\u7269\u533b\u7528\u6750\u6599\u4e2d\u7684\u6f5c\u529b<\/h3>\n

\u7531\u4e8e\u5176\u4f4e\u6bd2\u6027\u548c\u826f\u597d\u7684\u751f\u7269\u76f8\u5bb9\u6027\uff0cNMMO\u5728\u751f\u7269\u533b\u836f\u6750\u6599\u5408\u6210\u4e2d\u7684\u6f5c\u529b\u503c\u5f97\u8fdb\u4e00\u6b65\u6316\u6398\u3002<\/p>\n

3. \u5de5\u827a\u4f18\u5316\u4e0e\u6210\u672c\u63a7\u5236<\/h3>\n

\u76ee\u524dNMMO\u7684\u4ef7\u683c\u76f8\u5bf9\u8f83\u9ad8\uff0c\u82e5\u80fd\u5728\u751f\u4ea7\u5de5\u827a\u4e0a\u5b9e\u73b0\u7a81\u7834\uff0c\u5c06\u8fdb\u4e00\u6b65\u63a8\u52a8\u5176\u5728\u5de5\u4e1a\u9886\u57df\u7684\u666e\u53ca\u3002<\/p>\n

\n

\u7ed3\u8bed\uff1a\u6e29\u67d4\u7684\u529b\u91cf\u4e0d\u53ef\u5c0f\u89d1<\/h2>\n

\u5728\u8fd9\u4e2a\u8ffd\u6c42\u6548\u7387\u4e0e\u901f\u5ea6\u7684\u65f6\u4ee3\uff0cNMMO\u7528\u5b83\u7684\u201c\u6e29\u67d4\u201d\u544a\u8bc9\u6211\u4eec\uff1a\u6709\u65f6\u5019\uff0c\u6162\u4e00\u70b9\u3001\u7a33\u4e00\u70b9\uff0c\u53cd\u800c\u8d70\u5f97\u66f4\u8fdc\u3002<\/p>\n

\u5b83\u4e0d\u662f\u90a3\u79cd\u8f70\u8f70\u70c8\u70c8\u3001\u8ba9\u4eba\u773c\u524d\u4e00\u4eae\u7684\u201c\u660e\u661f\u6c27\u5316\u5242\u201d\uff0c\u4f46\u5b83\u5c31\u50cf\u4e00\u4e2a\u9ed8\u9ed8\u8015\u8018\u7684\u8001\u670b\u53cb\uff0c\u5728\u6bcf\u4e00\u4e2a\u9700\u8981\u6e29\u67d4\u4ee5\u5f85\u7684\u53cd\u5e94\u4e2d\uff0c\u9759\u9759\u5730\u5b88\u62a4\u7740\u805a\u5408\u7269\u4e16\u754c\u7684\u79e9\u5e8f\u4e0e\u7f8e\u597d\u3002<\/p>\n

\u6b63\u5982\u4e00\u4f4d\u56fd\u5916\u5b66\u8005\u5728\u5176\u8bba\u6587\u4e2d\u6240\u8a00\uff1a\u201cIn the world of oxidation, sometimes less is more.\u201d\uff08\u5728\u6c27\u5316\u7684\u4e16\u754c\u91cc\uff0c\u6709\u65f6\u5c11\u5373\u662f\u591a\u3002\uff09<\/p>\n

\u800c\u53e6\u4e00\u4f4d\u56fd\u5185\u4e13\u5bb6\u5219\u5f62\u8c61\u5730\u8bf4\uff1a\u201cNMMO\u662f\u4e00\u4f4d\u61c2\u5f97\u514b\u5236\u7684\u5316\u5b66\u5bb6\u3002\u201d\u2014\u2014\u8fd9\u6216\u8bb8\u662f\u5bf9\u5b83\u8d34\u5207\u7684\u8d5e\u7f8e\u3002<\/p>\n

\n

\u53c2\u8003\u6587\u732e<\/h2>\n

\u56fd\u5185\u6587\u732e\uff1a<\/h3>\n
    \n
  1. \u738b\u6653\u4e1c, \u674e\u534e. N-\u7532\u57fa\u5417\u5549\u6c27\u5316\u7269\u5728Lyocell\u7ea4\u7ef4\u751f\u4ea7\u4e2d\u7684\u5e94\u7528\u7814\u7a76[J]. \u9ad8\u5206\u5b50\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b, 2020, 36(3): 88-92.<\/li>\n
  2. \u5218\u5fd7\u5f3a, \u5f20\u4e3d. NMMO\u8f85\u52a9\u7684\u53ef\u63a7\u81ea\u7531\u57fa\u805a\u5408\u65b0\u8fdb\u5c55[J]. \u5408\u6210\u6811\u8102\u53ca\u5851\u6599, 2021, 38(2): 45-50.<\/li>\n
  3. \u9648\u660e, \u9ec4\u4f1f. \u7eff\u8272\u6c27\u5316\u5242NMMO\u5728\u9ad8\u5206\u5b50\u5408\u6210\u4e2d\u7684\u7814\u7a76\u8fdb\u5c55[J]. \u5e94\u7528\u5316\u5b66, 2022, 39(5): 601-608.<\/li>\n<\/ol>\n

    \u56fd\u5916\u6587\u732e\uff1a<\/h3>\n
      \n
    1. Heinze T, Liebert T F. Unconventional methods in cellulose functionalization. Progress in Polymer Science<\/em>, 2001, 26(8): 1689-1762.<\/li>\n
    2. Zhang Y, et al. N-Methylmorpholine N-oxide as a versatile mediator for controlled\/living radical polymerization. Macromolecules<\/em>, 2015, 48(12): 4029\u20134040.<\/li>\n
    3. Barner-Kowollik C, et al. Precision polymers by reversible-deactivation radical polymerizations: synthesis and materials applications. Nature Reviews Materials<\/em>, 2016, 1: 15010.<\/li>\n<\/ol>\n
      \n

      \u4f5c\u8005\u6309<\/strong>\uff1a\u5199\u4f5c\u6b64\u6587\u65f6\uff0c\u6211\u8bd5\u56fe\u4ee5\u8f7b\u677e\u5e7d\u9ed8\u53c8\u4e0d\u5931\u4e25\u8c28\u7684\u6001\u5ea6\u53bb\u8bb2\u8ff0\u4e00\u4e2a\u770b\u4f3c\u67af\u71e5\u7684\u5316\u5b66\u8bdd\u9898\u3002\u5e0c\u671b\u8fd9\u7bc7\u6587\u7ae0\u80fd\u8ba9\u8bfb\u8005\u611f\u53d7\u5230\u5316\u5b66\u7684\u9b45\u529b\uff0c\u4e5f\u80fd\u8ba9\u5927\u5bb6\u91cd\u65b0\u8ba4\u8bc6\u8fd9\u4f4d\u4f4e\u8c03\u5374\u5b9e\u529b\u975e\u51e1\u7684\u201c\u6e29\u67d4\u6d3e\u201d\u9009\u624b\u2014\u2014NMMO\u3002<\/p>\n

      ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

      \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

      \u624b\u673a\u53f7\u7801\uff1a 18301903156 (\u5fae\u4fe1\u540c\u53f7)<\/h2>\n

      \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

      \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

      ===========================================================<\/p>\n

      \u516c\u53f8\u5176\u5b83\u4ea7\u54c1\u5c55\u793a:<\/h2>\n
        \n
      • \n

        NT CAT T-12 \u9002\u7528\u4e8e\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff0c\u5feb\u901f\u56fa\u5316\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT UL1 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6d3b\u6027\u7565\u4f4e\u4e8eT-12\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT UL22 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\uff0c\u4f18\u5f02\u7684\u8010\u6c34\u89e3\u6027\u80fd\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT UL28 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u6d3b\u6027\u9ad8\uff0c\u5e38\u7528\u4e8e\u66ff\u4ee3T-12\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT UL30 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT UL50 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT UL54 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u8010\u6c34\u89e3\u6027\u826f\u597d\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT SI220 \u9002\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u7279\u522b\u63a8\u8350\u7528\u4e8eMS\u80f6\uff0c\u6d3b\u6027\u6bd4T-12\u9ad8\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT MB20 \u9002\u7528\u6709\u673a\u94cb\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u6709\u673a\u7845\u4f53\u7cfb\u548c\u7845\u70f7\u6539\u6027\u805a\u5408\u7269\u4f53\u7cfb\uff0c\u6d3b\u6027\u8f83\u4f4e\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n
      • \n

        NT CAT DBU \u9002\u7528\u6709\u673a\u80fa\u7c7b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u5ba4\u6e29\u786b\u5316\u7845\u6a61\u80f6\uff0c\u6ee1\u8db3\u5404\u7c7b\u73af\u4fdd\u6cd5\u89c4\u8981\u6c42\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

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