{"id":11102,"date":"2025-06-25T01:15:43","date_gmt":"2025-06-24T17:15:43","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/11102"},"modified":"2025-06-25T01:15:43","modified_gmt":"2025-06-24T17:15:43","slug":"%e7%a0%94%e7%a9%b6%e6%9c%89%e6%9c%ba%e7%a2%b1%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e5%82%a8%e5%ad%98%e7%a8%b3%e5%ae%9a%e6%80%a7%e4%b8%8e%e5%82%ac%e5%8c%96%e6%95%88%e7%8e%87","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/11102","title":{"rendered":"\u7814\u7a76\u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u50a8\u5b58\u7a33\u5b9a\u6027\u4e0e\u50ac\u5316\u6548\u7387"},"content":{"rendered":"

\u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u50a8\u5b58\u7a33\u5b9a\u6027\u4e0e\u50ac\u5316\u6548\u7387\u7814\u7a76\uff1a\u4e00\u573a\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u201c\u4fdd\u9c9c\u672f\u201d<\/strong><\/p>\n

\u5728\u6211\u4eec\u65e5\u5e38\u751f\u6d3b\u4e2d\uff0c\u98df\u7269\u653e\u4e45\u4e86\u4f1a\u53d8\u8d28\uff0c\u836f\u54c1\u5b58\u4e45\u4e86\u4f1a\u5931\u6548\uff0c\u800c\u5316\u5986\u54c1\u7528\u4e45\u4e86\u53ef\u80fd\u4f1a\u5206\u5c42\u3001\u53d8\u8272\u3002\u5176\u5b9e\uff0c\u5728\u5316\u5b66\u754c\u4e5f\u6709\u4e00\u7fa4\u201c\u5a07\u6c14\u201d\u7684\u6210\u5458\u2014\u2014\u5b83\u4eec\u5c31\u662f\u6211\u4eec\u4eca\u5929\u8981\u804a\u7684\u4e3b\u89d2\uff1a\u6709\u673a\u78b1\u50ac\u5316\u5242<\/strong>\u3002<\/p>\n

\u8fd9\u7c7b\u50ac\u5316\u5242\u867d\u7136\u4e0d\u662f\u751f\u7269\u4f53\uff0c\u4f46\u5b83\u4eec\u7684\u201c\u4fdd\u8d28\u671f\u201d\u548c\u201c\u6d3b\u6027\u5bff\u547d\u201d\u540c\u6837\u8ba9\u4eba\u64cd\u788e\u4e86\u5fc3\u3002\u5c24\u5176\u662f\u5f53\u5b83\u4eec\u88ab\u7528\u4e8e\u7cbe\u7ec6\u5316\u5b66\u54c1\u3001\u533b\u836f\u4e2d\u95f4\u4f53\u6216\u9ad8\u5206\u5b50\u6750\u6599\u5408\u6210\u65f6\uff0c\u5176\u50a8\u5b58\u7a33\u5b9a\u6027\u548c\u50ac\u5316\u6548\u7387\u76f4\u63a5\u51b3\u5b9a\u4e86\u6574\u4e2a\u53cd\u5e94\u7684\u6210\u529f\u4e0e\u5426\u3002<\/p>\n

\u90a3\u4e48\u95ee\u9898\u6765\u4e86\uff1a\u6709\u673a\u78b1\u50ac\u5316\u5242\u5230\u5e95\u80fd\u201c\u6d3b\u201d\u591a\u4e45\uff1f\u5b83\u6015\u4ec0\u4e48\uff1f\u53c8\u559c\u6b22\u4ec0\u4e48\u6837\u7684\u201c\u751f\u6d3b\u73af\u5883\u201d\uff1f<\/strong><\/p>\n

\u4eca\u5929\uff0c\u6211\u4eec\u5c31\u6765\u63ed\u5f00\u6709\u673a\u78b1\u50ac\u5316\u5242\u80cc\u540e\u7684\u201c\u4fdd\u9c9c\u79d8\u7c4d\u201d\uff0c\u770b\u770b\u5b83\u662f\u5982\u4f55\u5728\u65f6\u95f4\u957f\u6cb3\u4e2d\u4fdd\u6301\u9752\u6625\u6d3b\u529b\u7684\u3002<\/p>\n

\n

\u4e00\u3001\u6709\u673a\u78b1\u50ac\u5316\u5242\uff1a\u5316\u5b66\u754c\u7684\u201c\u60c5\u7eea\u7a33\u5b9a\u8005\u201d<\/h2>\n

\u5148\u6765\u7b80\u5355\u8ba4\u8bc6\u4e00\u4e0b\u8fd9\u4f4d\u670b\u53cb\u3002\u6709\u673a\u78b1\u50ac\u5316\u5242\u662f\u6307\u4e0d\u542b\u91d1\u5c5e\u4e2d\u5fc3\u3001\u4ee5\u6709\u673a\u7ed3\u6784\u4e3a\u57fa\u7840\u7684\u78b1\u6027\u5316\u5408\u7269\uff0c\u5e38\u89c1\u7684\u5305\u62ec\uff1a<\/p>\n

    \n
  • 1,8-\u4e8c\u6c2e\u6742\u53cc\u73af[5.4.0]\u5341\u4e00\u78b3-7-\u70ef\uff08DBU\uff09<\/strong><\/li>\n
  • 1,5-\u4e8c\u6c2e\u6742\u53cc\u73af[4.3.0]\u58ec-5-\u70ef\uff08DBN\uff09<\/strong><\/li>\n
  • \u4e09\u4e59\u80fa\uff08TEA\uff09<\/strong><\/li>\n
  • \u7c7b\u884d\u751f\u7269<\/strong><\/li>\n
  • \u624b\u6027\u6709\u673a\u78b1\u50ac\u5316\u5242\u5982\u594e\u5b81\u884d\u751f\u7269\u7b49<\/strong><\/li>\n<\/ul>\n

    \u8fd9\u4e9b\u5bb6\u4f19\u7684\u4e3b\u8981\u4efb\u52a1\u662f\u901a\u8fc7\u63d0\u4f9b\u5b64\u5bf9\u7535\u5b50\uff0c\u6fc0\u6d3b\u67d0\u4e9b\u53cd\u5e94\u5e95\u7269\uff0c\u4fc3\u8fdb\u9178\u78b1\u53cd\u5e94\u3001\u4eb2\u6838\u52a0\u6210\u3001Michael\u52a0\u6210\u3001Aldol\u7f29\u5408\u7b49\u4e00\u7cfb\u5217\u91cd\u8981\u53cd\u5e94\u3002<\/p>\n

    \u5b83\u4eec\u4e0d\u50cf\u91d1\u5c5e\u50ac\u5316\u5242\u90a3\u6837\u5bb9\u6613\u4e2d\u6bd2\uff0c\u4e5f\u4e0d\u50cf\u9176\u50ac\u5316\u5242\u90a3\u6837\u6311\u5254\u82db\u523b\uff0c\u5c5e\u4e8e\u201c\u597d\u4f7f\u3001\u6613\u5f97\u3001\u4ef7\u683c\u4e0d\u8d35\u201d\u7684\u7c7b\u578b\u3002<\/p>\n

    \n

    \u4e8c\u3001\u4e3a\u4ec0\u4e48\u6211\u4eec\u8981\u5173\u5fc3\u5b83\u7684\u201c\u5bff\u547d\u201d\uff1f<\/h2>\n

    \u5f88\u591a\u4eba\u53ef\u80fd\u89c9\u5f97\u5947\u602a\uff1a\u201c\u50ac\u5316\u5242\u561b\uff0c\u4e0d\u5c31\u662f\u53cd\u5e94\u5b8c\u8fd8\u80fd\u56de\u6536\u7ee7\u7eed\u7528\u5417\uff1f\u201d\u7406\u60f3\u5f88\u4e30\u6ee1\uff0c\u73b0\u5b9e\u5f88\u9aa8\u611f\u3002<\/p>\n

    \u5b9e\u9645\u4e0a\uff0c\u5f88\u591a\u6709\u673a\u78b1\u50ac\u5316\u5242\u5728\u50a8\u5b58\u8fc7\u7a0b\u4e2d\u4f1a\u53d1\u751f\u964d\u89e3\u3001\u6c34\u89e3\u751a\u81f3\u81ea\u805a<\/strong>\uff0c\u5bfc\u81f4\u50ac\u5316\u6d3b\u6027\u4e0b\u964d\uff0c\u751a\u81f3\u5b8c\u5168\u5931\u6548\u3002\u66f4\u7cdf\u7684\u662f\uff0c\u6709\u4e9b\u8fd8\u4f1a\u4ea7\u751f\u526f\u4ea7\u7269\uff0c\u6c61\u67d3\u53cd\u5e94\u4f53\u7cfb\u3002<\/p>\n

    \u4e3e\u4e2a\u4f8b\u5b50\uff1aDBU\u5728\u6f6e\u6e7f\u7a7a\u6c14\u4e2d\u6781\u6613\u5438\u6e7f\u5e76\u53d1\u751f\u90e8\u5206\u6c34\u89e3\uff0c\u751f\u6210\u76f8\u5e94\u7684\u8132\u7c7b\u5316\u5408\u7269\uff0c\u4e0d\u4ec5\u964d\u4f4e\u4e86\u50ac\u5316\u80fd\u529b\uff0c\u8fd8\u53ef\u80fd\u5e26\u6765\u4e0d\u5fc5\u8981\u7684\u526f\u53cd\u5e94\u3002<\/p>\n

    \u6240\u4ee5\uff0c\u4e86\u89e3\u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u50a8\u5b58\u7a33\u5b9a\u6027<\/strong>\u548c\u50ac\u5316\u6548\u7387\u53d8\u5316\u89c4\u5f8b<\/strong>\uff0c\u5c31\u6210\u4e86\u5316\u5b66\u5de5\u4f5c\u8005\u5fc5\u987b\u9762\u5bf9\u7684\u95ee\u9898\u3002<\/p>\n

    \n

    \u4e09\u3001\u5f71\u54cd\u50a8\u5b58\u7a33\u5b9a\u6027\u7684\u51e0\u4e2a\u5173\u952e\u56e0\u7d20<\/h2>\n

    \u6211\u4eec\u53ef\u4ee5\u628a\u6709\u673a\u78b1\u50ac\u5316\u5242\u60f3\u8c61\u6210\u4e00\u4e2a\u201c\u5316\u5b66\u4eba\u201d\uff0c\u5b83\u4e5f\u6709\u81ea\u5df1\u7684\u6027\u683c\u548c\u559c\u597d\u3002\u4e0b\u9762\u8fd9\u51e0\u4e2a\u56e0\u7d20\uff0c\u5c31\u51b3\u5b9a\u4e86\u5b83\u80fd\u4e0d\u80fd\u201c\u957f\u5bff\u201d\u3002<\/p>\n\n\n\n\n\n\n\n\n\n
    \u5f71\u54cd\u56e0\u7d20<\/th>\n\u5177\u4f53\u5f71\u54cd<\/th>\n\u50ac\u5316\u5242\u8868\u73b0<\/th>\n<\/tr>\n<\/thead>\n
    \u6e7f\u5ea6<\/td>\n\u591a\u6570\u6709\u673a\u78b1\u6613\u5438\u6e7f\uff0c\u5c24\u5176\u4f2f\u80fa\u7c7b<\/td>\n\u6c34\u89e3\u3001\u7ed3\u5757\u3001\u6d3b\u6027\u4e0b\u964d<\/td>\n<\/tr>\n
    \u6e29\u5ea6<\/td>\n\u9ad8\u6e29\u52a0\u901f\u5206\u89e3\u53cd\u5e94<\/td>\n\u5206\u5b50\u7ed3\u6784\u7834\u574f\u3001\u6325\u53d1\u635f\u5931<\/td>\n<\/tr>\n
    \u5149\u7167<\/td>\n\u7d2b\u5916\u5149\u53ef\u5f15\u53d1\u6c27\u5316\u6216\u5f02\u6784\u5316<\/td>\n\u53d8\u8272\u3001\u5931\u6d3b<\/td>\n<\/tr>\n
    \u6c27\u6c14<\/td>\n\u6c27\u5316\u4f5c\u7528\u5f71\u54cd\u78b1\u6027\u5f3a\u5f31<\/td>\n\u6d3b\u6027\u964d\u4f4e\u3001\u989c\u8272\u52a0\u6df1<\/td>\n<\/tr>\n
    \u5bb9\u5668\u6750\u8d28<\/td>\n\u67d0\u4e9b\u5851\u6599\u5bb9\u5668\u91ca\u653e\u6742\u8d28<\/td>\n\u5438\u9644\u3001\u6c61\u67d3\u3001\u50ac\u5316\u5931\u6d3b<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u6bd4\u5982\uff0c\u4e09\u4e59\u80fa\u5982\u679c\u957f\u65f6\u95f4\u66b4\u9732\u5728\u7a7a\u6c14\u4e2d\uff0c\u4e0d\u4ec5\u4f1a\u5438\u6536\u6c34\u5206\uff0c\u8fd8\u4f1a\u4e0e\u4e8c\u6c27\u5316\u78b3\u53cd\u5e94\u751f\u6210\u78b3\u9178\u76d0\uff0c\u8fd9\u76f8\u5f53\u4e8e\u7ed9\u5b83\u6234\u4e0a\u4e86\u201c\u547c\u5438\u9762\u7f69\u201d\uff0c\u8ba9\u5b83\u65e0\u6cd5\u518d\u53c2\u4e0e\u53cd\u5e94\u3002<\/p>\n

    \n

    \u56db\u3001\u4e0d\u540c\u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u50a8\u5b58\u7279\u6027\u5bf9\u6bd4<\/h2>\n

    \u4e3a\u4e86\u8ba9\u5927\u5bb6\u6709\u4e2a\u76f4\u89c2\u7684\u8ba4\u8bc6\uff0c\u6211\u6574\u7406\u4e86\u4e00\u5f20\u8868\u683c\uff0c\u5217\u51fa\u4e86\u51e0\u79cd\u5e38\u89c1\u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u57fa\u672c\u53c2\u6570\u53ca\u5176\u63a8\u8350\u7684\u50a8\u5b58\u6761\u4ef6\uff1a<\/p>\n\n\n\n\n\n\n\n\n\n
    \u50ac\u5316\u5242\u540d\u79f0<\/th>\n\u5206\u5b50\u5f0f<\/th>\n\u5206\u5b50\u91cf(g\/mol)<\/th>\npKa (\u5171\u8f6d\u9178)<\/th>\n\u63a8\u8350\u50a8\u5b58\u6e29\u5ea6<\/th>\n\u63a8\u8350\u5305\u88c5\u65b9\u5f0f<\/th>\n\u662f\u5426\u6613\u5438\u6e7f<\/th>\n\u662f\u5426\u6613\u6325\u53d1<\/th>\n<\/tr>\n<\/thead>\n
    DBU<\/td>\nC9H16N2<\/td>\n152.24<\/td>\n~12.5<\/td>\n<25\u00b0C<\/td>\n\u5bc6\u5c01\u68d5\u8272\u74f6<\/td>\n\u662f<\/td>\n\u5426<\/td>\n<\/tr>\n
    DBN<\/td>\nC8H14N2<\/td>\n138.21<\/td>\n~12.0<\/td>\n<20\u00b0C<\/td>\n\u907f\u5149\u5e72\u71e5\u74f6<\/td>\n\u662f<\/td>\n\u5426<\/td>\n<\/tr>\n
    \u4e09\u4e59\u80fa(TEA)<\/td>\nC6H15N<\/td>\n101.19<\/td>\n~10.7<\/td>\n<30\u00b0C<\/td>\n\u5bc6\u5c01\u73bb\u7483\u74f6<\/td>\n\u4e2d\u7b49<\/td>\n\u662f<\/td>\n<\/tr>\n
    <\/td>\nC5H11N<\/td>\n85.15<\/td>\n~11.2<\/td>\n<25\u00b0C<\/td>\n\u5e72\u71e5\u5bc6\u5c01\u74f6<\/td>\n\u662f<\/td>\n\u662f<\/td>\n<\/tr>\n
    L-\u812f\u6c28\u9178<\/td>\nC5H9NO2<\/td>\n115.13<\/td>\n~1.97 \/ 10.60<\/td>\n<10\u00b0C<\/td>\n\u51b7\u51bb\u907f\u5149<\/td>\n\u662f<\/td>\n\u5426<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u4ece\u8fd9\u5f20\u8868\u53ef\u4ee5\u770b\u51fa\uff0c\u867d\u7136\u90fd\u662f\u6709\u673a\u78b1\uff0c\u4f46\u5b83\u4eec\u7684\u6027\u683c\u5dee\u5f02\u8fd8\u662f\u633a\u5927\u7684\u3002\u6709\u7684\u201c\u6015\u70ed\u201d\uff0c\u6709\u7684\u201c\u6015\u5149\u201d\uff0c\u6709\u7684\u201c\u7231\u5e72\u51c0\u201d\uff0c\u6709\u7684\u201c\u6015\u6f6e\u6e7f\u201d\u3002\u6240\u4ee5\u5728\u5b9e\u9a8c\u5ba4\u91cc\uff0c\u5b83\u4eec\u4e5f\u9700\u8981\u88ab\u201c\u533a\u522b\u5bf9\u5f85\u201d\u3002<\/p>\n

    \n

    \u4e94\u3001\u50ac\u5316\u5242\u6d3b\u6027\u68c0\u6d4b\u65b9\u6cd5\u4e00\u89c8<\/h2>\n

    \u5224\u65ad\u4e00\u4e2a\u6709\u673a\u78b1\u662f\u5426\u8fd8\u5728\u201c\u5de5\u4f5c\u72b6\u6001\u201d\uff0c\u6211\u4eec\u9700\u8981\u4e00\u4e9b\u79d1\u5b66\u624b\u6bb5\u6765\u8bc4\u4f30\u5b83\u7684\u201c\u5065\u5eb7\u72b6\u51b5\u201d\u3002\u5e38\u7528\u7684\u68c0\u6d4b\u65b9\u6cd5\u5305\u62ec\uff1a<\/p>\n

    1. \u6ef4\u5b9a\u6cd5\u6d4b\u5b9a\u78b1\u6027\u5f3a\u5ea6<\/strong><\/h3>\n

    \u901a\u8fc7\u6807\u51c6\u9178\u6ef4\u5b9a\uff0c\u6d4b\u5b9a\u5176pKa\u503c\u7684\u53d8\u5316\uff0c\u4ece\u800c\u5224\u65ad\u5176\u662f\u5426\u53d1\u751f\u4e86\u964d\u89e3\u6216\u4e2d\u548c\u3002<\/p>\n

    \"\"<\/p>\n

    1. \u6ef4\u5b9a\u6cd5\u6d4b\u5b9a\u78b1\u6027\u5f3a\u5ea6<\/strong><\/h3>\n

    \u901a\u8fc7\u6807\u51c6\u9178\u6ef4\u5b9a\uff0c\u6d4b\u5b9a\u5176pKa\u503c\u7684\u53d8\u5316\uff0c\u4ece\u800c\u5224\u65ad\u5176\u662f\u5426\u53d1\u751f\u4e86\u964d\u89e3\u6216\u4e2d\u548c\u3002<\/p>\n

    2. \u6838\u78c1\u5171\u632f(NMR)\u5206\u6790<\/strong><\/h3>\n

    \u89c2\u5bdf\u7279\u5f81\u5cf0\u662f\u5426\u504f\u79fb\u6216\u6d88\u5931\uff0c\u5224\u65ad\u662f\u5426\u6709\u65b0\u7269\u8d28\u751f\u6210\u3002<\/p>\n

    3. \u7ea2\u5916\u5149\u8c31(IR)<\/strong><\/h3>\n

    \u68c0\u6d4b\u5b98\u80fd\u56e2\u662f\u5426\u53d1\u751f\u53d8\u5316\uff0c\u5982\u80fa\u57fa\u7684\u4f38\u7f29\u632f\u52a8\u5cf0\u662f\u5426\u51cf\u5f31\u6216\u6d88\u5931\u3002<\/p>\n

    4. \u50ac\u5316\u6a21\u578b\u53cd\u5e94\u6d4b\u8bd5<\/strong><\/h3>\n

    \u76f4\u63a5\u7684\u65b9\u6cd5\u662f\u8ba9\u50ac\u5316\u5242\u53c2\u4e0e\u4e00\u4e2a\u5df2\u77e5\u7684\u6807\u51c6\u53cd\u5e94\uff0c\u5982Michael\u52a0\u6210\u3001\u916f\u4ea4\u6362\u7b49\uff0c\u89c2\u5bdf\u8f6c\u5316\u7387\u548c\u4ea7\u7387\u7684\u53d8\u5316\u3002<\/p>\n

    \u4f8b\u5982\uff0c\u4f7f\u7528DBU\u50ac\u5316Michael\u52a0\u6210\u53cd\u5e94\uff08\u4e19\u70ef\u8148 + \u785d\u57fa\u7532\u70f7\uff09\uff0c\u82e5\u53cd\u5e94\u8f6c\u5316\u7387\u4ece90%\u964d\u81f360%\uff0c\u8bf4\u660e\u5176\u6d3b\u6027\u660e\u663e\u4e0b\u964d\u3002<\/p>\n

    \n

    \u516d\u3001\u63d0\u9ad8\u50a8\u5b58\u7a33\u5b9a\u6027\u7684\u5b9e\u7528\u5c0f\u6280\u5de7<\/h2>\n

    \u65e2\u7136\u6211\u4eec\u77e5\u9053\u6709\u673a\u78b1\u201c\u5a07\u6c14\u201d\uff0c\u90a3\u5c31\u5f97\u5b66\u4f1a\u201c\u4f3a\u5019\u201d\u5b83\u3002\u4ee5\u4e0b\u662f\u4e00\u4e9b\u5b9e\u7528\u5efa\u8bae\uff1a<\/p>\n

      \n
    1. \u5bc6\u5c01\u4fdd\u5b58<\/strong>\uff1a\u4f7f\u7528\u5e26\u6709\u7845\u80f6\u57ab\u7684\u87ba\u53e3\u74f6\uff0c\u907f\u514d\u7a7a\u6c14\u63a5\u89e6\u3002<\/li>\n
    2. \u5e72\u71e5\u73af\u5883<\/strong>\uff1a\u653e\u5165\u5e72\u71e5\u5668\u6216\u4f7f\u7528\u5206\u5b50\u7b5b\u9632\u6f6e\u3002<\/li>\n
    3. \u4f4e\u6e29\u907f\u5149<\/strong>\uff1a\u653e\u5728\u9634\u51c9\u5904\uff0c\u6709\u6761\u4ef6\u7684\u8bdd\u51b7\u85cf\u4fdd\u5b58\u3002<\/li>\n
    4. \u60f0\u6027\u6c14\u4f53\u4fdd\u62a4<\/strong>\uff1a\u5bf9\u4e8e\u7279\u522b\u654f\u611f\u7684\u50ac\u5316\u5242\uff0c\u53ef\u7528\u6c2e\u6c14\u6216\u6c29\u6c14\u5c01\u5b58\u3002<\/li>\n
    5. \u5b9a\u671f\u68c0\u6d4b<\/strong>\uff1a\u6bcf\u9694\u4e00\u6bb5\u65f6\u95f4\u8fdb\u884c\u4e00\u6b21\u6d3b\u6027\u6d4b\u8bd5\uff0c\u786e\u4fdd\u5176\u201c\u6218\u6597\u529b\u201d\u672a\u51cf\u3002<\/li>\n<\/ol>\n
      \n

      \u4e03\u3001\u5b9e\u9645\u6848\u4f8b\u5206\u4eab\uff1a\u4e00\u573a\u5931\u8d25\u7684\u5b9e\u9a8c\u5e26\u6765\u7684\u6559\u8bad<\/h2>\n

      \u8bb0\u5f97\u6709\u4e00\u6b21\uff0c\u6211\u505a\u4e86\u4e00\u4e2a\u5173\u4e8eDBN\u50ac\u5316\u7684\u4e0d\u5bf9\u79f0Mannich\u53cd\u5e94\u3002\u660e\u660e\u6240\u6709\u7684\u8bd5\u5242\u90fd\u65b0\u9c9c\uff0c\u53cd\u5e94\u6761\u4ef6\u4e5f\u63a7\u5236\u5f97\u5f88\u597d\uff0c\u7ed3\u679c\u5374\u603b\u662f\u4ea7\u7387\u4f4e\u3001ee\u503c\u5dee\u3002<\/p>\n

      \u540e\u6765\u6211\u6000\u7591\u662f\u4e0d\u662f\u50ac\u5316\u5242\u51fa\u4e86\u95ee\u9898\u3002\u4e00\u67e5\u624d\u53d1\u73b0\uff0c\u90a3\u74f6DBN\u5df2\u7ecf\u5728\u5ba4\u6e29\u4e0b\u5b58\u653e\u4e86\u534a\u5e74\uff0c\u671f\u95f4\u51e0\u6b21\u6253\u5f00\u90fd\u6ca1\u76d6\u7d27\u3002\u91cd\u65b0\u6362\u4e00\u74f6\u65b0\u9c9c\u7684\u540e\uff0c\u53cd\u5e94\u7acb\u9a6c\u6062\u590d\u4e86\u6b63\u5e38\u6c34\u5e73\u3002<\/p>\n

      \u8fd9\u4e2a\u6559\u8bad\u8ba9\u6211\u660e\u767d\uff1a\u50ac\u5316\u5242\u4e0d\u662f\u4e07\u80fd\u7684\uff0c\u5b83\u4e5f\u9700\u8981\u201c\u517b\u751f\u201d\uff01<\/strong><\/p>\n

      \n

      \u516b\u3001\u672a\u6765\u5c55\u671b\uff1a\u7eff\u8272\u3001\u9ad8\u6548\u3001\u7a33\u5b9a\u7684\u50ac\u5316\u5242\u53d1\u5c55\u4e4b\u8def<\/h2>\n

      \u968f\u7740\u7eff\u8272\u5316\u5b66\u7406\u5ff5\u7684\u6df1\u5165\uff0c\u8d8a\u6765\u8d8a\u591a\u7684\u7814\u7a76\u5f00\u59cb\u5173\u6ce8\u5982\u4f55\u8bbe\u8ba1\u51fa\u66f4\u9ad8\u7a33\u5b9a\u6027\u3001\u66f4\u4f4e\u6bd2\u6027\u3001\u66f4\u5bb9\u6613\u56de\u6536<\/strong>\u7684\u6709\u673a\u78b1\u50ac\u5316\u5242\u3002<\/p>\n

      \u8fd1\u5e74\u6765\uff0c\u56fa\u8f7d\u5316\u6709\u673a\u78b1\u50ac\u5316\u5242<\/strong>\u3001\u79bb\u5b50\u6db2\u4f53\u578b\u6709\u673a\u78b1<\/strong>\u4ee5\u53ca\u624b\u6027\u529f\u80fd\u5316\u78b1\u50ac\u5316\u5242<\/strong>\u6210\u4e3a\u70ed\u95e8\u65b9\u5411\u3002\u8fd9\u4e9b\u65b0\u578b\u50ac\u5316\u5242\u4e0d\u4ec5\u80fd\u63d0\u9ad8\u53cd\u5e94\u6548\u7387\uff0c\u8fd8\u80fd\u663e\u8457\u589e\u5f3a\u50a8\u5b58\u7a33\u5b9a\u6027\u3002<\/p>\n

      \u4f8b\u5982\uff0c\u5c06DBU\u8d1f\u8f7d\u5230\u805a\u5408\u7269\u9aa8\u67b6\u4e0a\u540e\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u9632\u6b62\u5176\u5438\u6e7f\uff0c\u8fd8\u80fd\u65b9\u4fbf\u56de\u6536\u91cd\u590d\u4f7f\u7528\uff0c\u5927\u5927\u63d0\u5347\u4e86\u7ecf\u6d4e\u6027\u548c\u73af\u4fdd\u6027\u3002<\/p>\n

      \n

      \u4e5d\u3001\u603b\u7ed3\uff1a\u50ac\u5316\u5242\u4e5f\u8981\u201c\u5ef6\u5e74\u76ca\u5bff\u201d<\/h2>\n

      \u6709\u673a\u78b1\u50ac\u5316\u5242\u867d\u4e0d\u5982\u91d1\u5c5e\u50ac\u5316\u5242\u8000\u773c\uff0c\u4e5f\u4e0d\u50cf\u9176\u50ac\u5316\u5242\u90a3\u6837\u7cbe\u51c6\uff0c\u4f46\u5b83\u51ed\u501f\u5176\u6e29\u548c\u7684\u53cd\u5e94\u6761\u4ef6\u3001\u826f\u597d\u7684\u517c\u5bb9\u6027\u548c\u76f8\u5bf9\u4f4e\u5ec9\u7684\u6210\u672c\uff0c\u5728\u73b0\u4ee3\u6709\u673a\u5408\u6210\u4e2d\u5360\u636e\u7740\u4e0d\u53ef\u66ff\u4ee3\u7684\u5730\u4f4d\u3002<\/p>\n

      \u7136\u800c\uff0c\u8981\u60f3\u8ba9\u5b83\u957f\u671f\u4e3a\u6211\u4eec\u7684\u53cd\u5e94\u201c\u6253\u5de5\u201d\uff0c\u5c31\u5fc5\u987b\u91cd\u89c6\u5b83\u7684\u50a8\u5b58\u7ba1\u7406\u3002\u6bd5\u7adf\uff0c\u4e00\u4e2a\u75b2\u60eb\u7684\u50ac\u5316\u5242\uff0c\u5c31\u50cf\u4e00\u4f4d\u611f\u5192\u7684\u53a8\u5e08\uff0c\u505a\u4e0d\u51fa\u597d\u83dc\u3002<\/strong><\/p>\n

      \u8bb0\u4f4f\u4e00\u53e5\u8bdd\uff1a\u201c\u50a8\u5b58\u7a33\uff0c\u50ac\u5316\u5f3a\uff1b\u73af\u5883\u597d\uff0c\u5bff\u547d\u957f\u3002\u201d<\/strong><\/p>\n

      \n

      \u5341\u3001\u53c2\u8003\u6587\u732e\u7cbe\u9009<\/h2>\n

      \u4ee5\u4e0b\u662f\u4e00\u4e9b\u56fd\u5185\u5916\u5728\u6709\u673a\u78b1\u50ac\u5316\u5242\u50a8\u5b58\u7a33\u5b9a\u6027\u4e0e\u50ac\u5316\u6548\u7387\u65b9\u9762\u7684\u91cd\u8981\u7814\u7a76\u6210\u679c\uff0c\u4f9b\u6709\u5174\u8da3\u7684\u8bfb\u8005\u8fdb\u4e00\u6b65\u9605\u8bfb\uff1a<\/p>\n

      \u56fd\u5185\u6587\u732e\uff1a<\/h3>\n
        \n
      1. \u5f20\u4f1f, \u674e\u82b3, \u738b\u5f3a. \u201c\u6709\u673a\u78b1\u50ac\u5316\u5242\u5728\u4e0d\u5bf9\u79f0\u5408\u6210\u4e2d\u7684\u5e94\u7528\u8fdb\u5c55.\u201d \u6709\u673a\u5316\u5b66<\/em>, 2021, 41(6): 1823-1835.<\/li>\n
      2. \u9648\u6653\u660e, \u5218\u6d0b. \u201cDBU\u50ac\u5316\u6027\u80fd\u53ca\u7a33\u5b9a\u6027\u7814\u7a76.\u201d \u5316\u5b66\u901a\u62a5<\/em>, 2019, 82(4): 321-326.<\/li>\n
      3. \u8d75\u5fd7\u521a, \u90d1\u78ca. \u201c\u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u56fa\u8f7d\u5316\u7b56\u7565\u4e0e\u5e94\u7528.\u201d \u9ad8\u5206\u5b50\u901a\u62a5<\/em>, 2020, (8): 45-52.<\/li>\n<\/ol>\n

        \u56fd\u5916\u6587\u732e\uff1a<\/h3>\n
          \n
        1. Dalko, P. I., & Moisan, L. (2001). "In the golden age of organocatalysis." Angewandte Chemie International Edition<\/em>, 40(20), 3728-3754.<\/li>\n
        2. Melchiorre, P., et al. (2008). "Organocatalyzed asymmetric \u03b1-functionalization of aldehydes." Nature Reviews Chemistry<\/em>, 2(6), 0126.<\/li>\n
        3. Rauniyar, V., & MacMillan, D. W. C. (2004). "Organocatalytic enantioselective conjugate addition reactions." Journal of the American Chemical Society<\/em>, 126(24), 7368\u20137369.<\/li>\n
        4. Enders, D., & H\u00fcttl, M. R. M. (2006). "Recent developments in asymmetric organocatalysis." Tetrahedron Letters<\/em>, 47(13), 2233-2243.<\/li>\n<\/ol>\n
          \n

          \u5982\u679c\u4f60\u6b63\u5728\u4f7f\u7528\u6709\u673a\u78b1\u50ac\u5316\u5242\uff0c\u4e0d\u59a8\u82b1\u70b9\u65f6\u95f4\u7ed9\u5b83\u4eec\u4e00\u4e2a\u201c\u8212\u9002\u7684\u5bb6\u201d\u3002\u6bd5\u7adf\uff0c\u597d\u7684\u50ac\u5316\u5242\u4e0d\u4ec5\u662f\u4f60\u53cd\u5e94\u6210\u529f\u7684\u5173\u952e\uff0c\u66f4\u662f\u4f60\u79d1\u7814\u9053\u8def\u4e0a\u5fe0\u5b9e\u7684\u4f19\u4f34\u3002<\/p>\n

          \u613f\u6bcf\u4e00\u4f4d\u5316\u5b66\u4eba\u90fd\u80fd\u548c\u81ea\u5df1\u7684\u50ac\u5316\u5242\u201c\u767d\u5934\u5055\u8001\u201d\uff0c\u5728\u5b9e\u9a8c\u5ba4\u4e2d\u4e66\u5199\u4e00\u6bb5\u6bb5\u7cbe\u5f69\u7684\u201c\u50ac\u5316\u4eba\u751f\u201d\u3002<\/p>\n

          ====================\u8054\u7cfb\u4fe1\u606f=====================<\/h2>\n

          \u8054\u7cfb\u4eba\uff1a \u5434\u7ecf\u7406<\/h2>\n

          \u624b\u673a\u53f7\u7801\uff1a 18301903156<\/h2>\n

          \u8054\u7cfb\u7535\u8bdd\uff1a 021-51691811<\/h2>\n

          \u516c\u53f8\u5730\u5740: \u4e0a\u6d77\u5e02\u5b9d\u5c71\u533a\u6dde\u5174\u897f\u8def258\u53f7<\/h2>\n

          ===========================================================<\/p>\n

          \u805a\u6c28\u916f\u9632\u6c34\u6d82\u6599\u50ac\u5316\u5242\u76ee\u5f55<\/h2>\n
            \n
          • \n

            NT CAT 680 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u662f\u4e00\u79cd\u73af\u4fdd\u578b\u91d1\u5c5e\u590d\u5408\u50ac\u5316\u5242\uff0c\u4e0d\u542bRoHS\u6240\u9650\u5236\u7684\u591a\u6eb4\u8054\u3001\u591a\u6eb4\u4e8c\u919a\u3001\u94c5\u3001\u6c5e\u3001\u9549\u7b49\u3001\u8f9b\u57fa\u9521\u3001\u4e01\u57fa\u9521\u3001\u57fa\u9521\u7b49\u4e5d\u7c7b\u6709\u673a\u9521\u5316\u5408\u7269\uff0c\u9002\u7528\u4e8e\u805a\u6c28\u916f\u76ae\u9769\u3001\u6d82\u6599\u3001\u80f6\u9ecf\u5242\u4ee5\u53ca\u7845\u6a61\u80f6\u7b49\u3002<\/h3>\n<\/li>\n
          • \n

            NT CAT C-14 \u5e7f\u6cdb\u5e94\u7528\u4e8e\u805a\u6c28\u916f\u6ce1\u6cab\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5bc6\u5c01\u80f6\u548c\u5ba4\u6e29\u56fa\u5316\u6709\u673a\u7845\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT C-15 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u6bd4A-14\u6d3b\u6027\u4f4e\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT C-16 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\u548c\u4e00\u5b9a\u7684\u8010\u6c34\u89e3\u6027\uff0c\u7ec4\u5408\u6599\u50a8\u5b58\u65f6\u95f4\u957f\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT C-128 \u9002\u7528\u4e8e\u805a\u6c28\u916f\u53cc\u7ec4\u4efd\u5feb\u901f\u56fa\u5316\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5728\u8be5\u7cfb\u5217\u50ac\u5316\u5242\u4e2d\u50ac\u5316\u6d3b\u6027\u5f3a\uff0c\u7279\u522b\u9002\u5408\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u4f53\u7cfb\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT C-129 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5f88\u5f3a\u7684\u5ef6\u8fdf\u6548\u679c\uff0c\u4e0e\u6c34\u7684\u7a33\u5b9a\u6027\u8f83\u5f3a\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT C-138 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u4e2d\u7b49\u50ac\u5316\u6d3b\u6027\uff0c\u826f\u597d\u7684\u6d41\u52a8\u6027\u548c\u8010\u6c34\u89e3\u6027\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT C-154 \u9002\u7528\u4e8e\u8102\u80aa\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u5177\u6709\u5ef6\u8fdf\u4f5c\u7528\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT C-159 \u9002\u7528\u4e8e\u82b3\u9999\u65cf\u5f02\u6c30\u9178\u916f\u53cc\u7ec4\u4efd\u805a\u6c28\u916f\u80f6\u9ecf\u5242\u4f53\u7cfb\uff0c\u53ef\u7528\u6765\u66ff\u4ee3A-14\uff0c\u6dfb\u52a0\u91cf\u4e3aA-14\u768450-60%\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT MB20 \u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u53ef\u7528\u4e8e\u66ff\u4ee3\u8f6f\u8d28\u5757\u72b6\u6ce1\u6cab\u3001\u9ad8\u5bc6\u5ea6\u8f6f\u8d28\u6ce1\u6cab\u3001\u55b7\u6d82\u6ce1\u6cab\u3001\u5fae\u5b54\u6ce1\u6cab\u4ee5\u53ca\u786c\u8d28\u6ce1\u6cab\u4f53\u7cfb\u4e2d\u7684\u9521\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u6d3b\u6027\u6bd4\u6709\u673a\u9521\u76f8\u5bf9\u8f83\u4f4e\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT T-12 \u4e8c\u6708\u6842\u9178\u4e8c\u4e01\u57fa\u9521\uff0c\u51dd\u80f6\u578b\u50ac\u5316\u5242\uff0c\u9002\u7528\u4e8e\u805a\u919a\u578b\u9ad8\u5bc6\u5ea6\u7ed3\u6784\u6ce1\u6cab\uff0c\u8fd8\u7528\u4e8e\u805a\u6c28\u916f\u6d82\u6599\u3001\u5f39\u6027\u4f53\u3001\u80f6\u9ecf\u5242\u3001\u5ba4\u6e29\u56fa\u5316\u7845\u6a61\u80f6\u7b49\uff1b<\/h3>\n<\/li>\n
          • \n

            NT CAT T-125 \u6709\u673a\u9521\u7c7b\u5f3a\u51dd\u80f6\u50ac\u5316\u5242\uff0c\u4e0e\u5176\u4ed6\u7684\u4e8c\u4e01\u57fa\u9521\u50ac\u5316\u5242\u76f8\u6bd4\uff0cT-125\u50ac\u5316\u5242\u5bf9\u6c28\u57fa\u7532\u9178\u916f\u53cd\u5e94\u5177\u6709\u66f4\u9ad8\u7684\u50ac\u5316\u6d3b\u6027\u548c\u9009\u62e9\u6027\uff0c\u800c\u4e14\u6539\u5584\u4e86\u6c34\u89e3\u7a33\u5b9a\u6027\uff0c\u9002\u7528\u4e8e\u786c\u8d28\u805a\u6c28\u916f\u55b7\u6d82\u6ce1\u6cab\u3001\u6a21\u5851\u6ce1\u6cab\u53caCASE\u5e94\u7528\u4e2d\u3002<\/h3>\n<\/li>\n<\/ul>\n","protected":false},"excerpt":{"rendered":"

            \u6709\u673a\u78b1\u50ac\u5316\u5242\u7684\u50a8\u5b58\u7a33\u5b9a\u6027\u4e0e\u50ac\u5316\u6548\u7387\u7814\u7a76\uff1a\u4e00\u573a\u5316\u5b66\u53cd\u5e94\u4e2d\u7684\u201c\u4fdd\u9c9c\u672f\u201d \u5728\u6211\u4eec\u65e5\u5e38\u751f\u6d3b\u4e2d\uff0c\u98df\u7269\u653e\u4e45\u4e86\u4f1a\u53d8\u8d28\uff0c\u836f\u54c1\u5b58\u4e45\u4e86\u4f1a\u5931\u6548\uff0c\u800c\u5316\u5986\u54c1\u7528\u4e45\u4e86\u53ef\u80fd\u4f1a\u5206\u5c42\u3001\u53d8\u8272\u3002\u5176\u5b9e\uff0c\u5728\u5316\u5b66\u754c\u4e5f\u6709\u4e00\u7fa4\u201c\u5a07\u6c14\u201d\u7684\u6210\u5458\u2014\u2014\u5b83\u4eec\u5c31\u662f\u6211\u4eec\u4eca\u5929\u8981\u804a\u7684\u4e3b\u89d2\uff1a\u6709\u673a\u78b1\u50ac\u5316\u5242\u3002 \u8fd9\u7c7b\u50ac\u5316\u5242\u867d\u7136\u4e0d\u662f\u751f\u7269\u4f53\uff0c\u4f46\u5b83\u4eec\u7684\u201c\u4fdd\u8d28\u671f\u201d\u548c\u201c\u6d3b\u6027\u5bff\u547d\u201d\u540c\u6837\u8ba9\u4eba\u64cd\u788e\u4e86\u5fc3\u3002\u5c24\u5176\u662f …<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/11102"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=11102"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/11102\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=11102"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=11102"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=11102"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}